Fluorinated polymers

被引：164
|
作者：
Imae, T [1 ]
机构：
[1] Nagoya Univ, Math Sci Res Ctr, Nagoya, Aichi 4648602, Japan
来源：
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE | 2003年 / 8卷 / 03期
关键词：
fluorinated polymer; homopolymer; block copolymer; diblock copolymer; multiblock copolymer; cross-link; network; ionomer;
D O I：
10.1016/S1359-0294(03)00050-5
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Up to date synthesis and properties of various types of fluorine-containing polymers have been reviewed. Homopolymers, which were fluorinated in main chain, terminal, and side chain, and perfluorinated ionomers, where a perfluoro pendant side chain was terminated by an ionic group, were synthesized and characterized. Polymer blocks with fluorinated side chain were combined with nonfluorinated blocks to prepare diblock and multiblock copolymers. Fluorinated cross-link was synthesized from perfluoroalkyl polymer by using the cross linking agent or from fluoro polymer by radiation modification. Fluorine-containing polymers aggregate in solutions by the solvophobic interaction of fluorinated moieties and form thin films with the segmented fluorine distribution. (C) 2003 Elsevier Ltd. All rights reserved.
引用
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页码：307 / 314
页数：8
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