Four new isostructural metal-organic frameworks constructed by a new butterfly-typed nitroheterocyclic carboxylic acid: Synthesis, crystal structures and properties

被引：0
作者：
Pi, Qiu [1 ]
Wang, Yan-Jiang [1 ]
Sun, Ya-Ya [1 ]
Wu, Ya-Pan [1 ]
Wu, Xue-Qian [1 ]
Li, Yong-Shuang [1 ]
Li, Dong-Sheng [1 ,2 ]
机构：
[1] China Three Gorges Univ, Coll Mat & Chem Engn, Key Lab Inorgan Nonmetall Crystalline & Energy Co, Yichang 443002, Hubei, Peoples R China
[2] Hubei Three Gorges Lab, Yichang 443007, Hubei, Peoples R China
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2022年 / 305卷
关键词：
4,6-di-1H-1,2,4-triazol-1-yi-1,3-benzenedicarboxylic acid; Coordination polymers; Crystal structure; Composite materials; Methanol oxidation; OXIDATION; MOFS; ELECTROCATALYST;
D O I：
10.1016/j.jssc.2021.122617
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Four new isostructural coordination polymers, [M-2(mu(2)-H2O)(DTBC)(2)] (CTGU- 26(M), M = Zn, Cd, Co and Ni] have been prepared with a new butterfly-typed nitroheterocyclic 4,6-di- 1H-1,2,4-triazol-1-yi-1,3-benzenedicarboxylic acid(H2DTBC) ligand and metal salts under hydrothermal condition. CTGU-26(Zn) features an unusual 2-nodal (4, 8)-connected scu topological network generated by [Zn-2(mu(2)-H2O)(COO)(4)] units and DTBC2- anion linkers. Luminescent properties measurements indicate that both CTGU-26(Zn) and CTGU-26(Cd) show intense fluorescence-emission compared with free H2DTBC ligand in solid state. Moreover, the electrocatalytic activities of CTGU-26(Co) and CTGU-26(Ni) towards methanol oxidation reaction (MOR) of two compounds were also investigated. Remarkably, by combining each MOF with the conducive 2,3,6,7,10,11-hexahydroxytriphenylene(HHTP) additive, a composite material, HHTP/CTGU-26(Ni)-I was confirmed to have an excellent performance for MOR with a high mass specific peak current of 25.55 mA cm(-2).
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页数：6
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