Bis[μ-bis(4-nitrophenyl)phosphato-κ2O:O′]bis{[bis(2-pyridylmethyl)amine-κ3N,N′,N′"]copper(II)} diperchlorate acetonitrile hemisolvate

被引：5

作者：

Butcher, RJ ^{[1
]}

Gultneh, Y ^{[1
]}

Allwar ^{[1
]}

机构：

[1] Howard Univ, Dept Chem, Washington, DC 20059 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷

关键词：

D O I：

10.1107/S160053680500992X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Cu-2(bnpp)(2)(bpa)(2)](ClO4)(2)center dot 0.5CH(3)CN [bpa is bis(2-pyridylmethyl)amine (C12H13N3) and bnpp is bis(4-nitrophenyl)phosphate (C12H8N2O8P)], contains two Cu-II ions, each coordinated in a distorted square-pyramidal geometry formed by the tridentate chelating ligand bpa and two O-atom donors from two bnpp ligands. Two bnpp anions bridge two Cu-II ions to form the dinuclear complex cation, one O-atom donor of each bnpp coordinating in a basal site and another coordinating in the apical position with a Jahn-Teller elongated bond of 2.189 ( 4) or 2.244 ( 3) angstrom.

引用

页码：M818 / M821

页数：4

共 36 条

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