Simple reversible fixation of a magnetic catalyst in a continuous flow system: ultrafast reduction of nitroarenes and subsequent reductive amination using ammonia borane

被引：12

作者：

Kim, Hong Won ^{[1
,2
]}

Byun, Sangmoon ^{[3
]}

Kim, Seong Min ^{[1
,2
]}

Kim, Ha Joon ^{[1
,2
]}

Lei, Cao ^{[1
,2
]}

Kang, Dong Yun ^{[1
,2
]}

Cho, Ahra ^{[3
]}

Kim, B. Moon ^{[3
]}

Park, Jin Kyoon ^{[1
,2
]}

机构：

[1] Pusan Natl Univ, Dept Chem, Busan 46241, South Korea

[2] Pusan Natl Univ, Chem Inst Funct Mat, Busan 46241, South Korea

[3] Seoul Natl Univ, Dept Chem, Seoul 08826, South Korea

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2020年 / 10卷 / 04期

基金：

新加坡国家研究基金会;

关键词：

TAMING HAZARDOUS CHEMISTRY; HYDROGENATION; NANOPARTICLES; ROBUST; ND;

D O I：

10.1039/c9cy02021g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Continuous reductive amination of aldehydes with nitroarenes over a Pd-Pt-Fe3O4 catalyst was performed. We used NH3BH3 as not only a hydrogen source for nitro reduction, but also a reductant for imine reduction. Secondary aromatic amines were obtained in the continuous flow reaction in good to excellent yields.

引用

页码：944 / 949

页数：6

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