Widely Tunable, Photoinvertible Cholesteric Liquid Crystals

被引:97
作者
White, Timothy J. [1 ]
Cazzell, Seth A. [1 ]
Freer, Alexander S. [1 ,3 ]
Yang, Deng-Ke [2 ]
Sukhomlinova, Ludmila [4 ]
Su, Linli [4 ]
Kosa, Tamas [4 ]
Taheri, Bahman [4 ]
Bunning, Timothy J. [1 ]
机构
[1] USAF, Res Lab, Mat & Mfg Directorate, Wright Patterson AFB, OH 45433 USA
[2] Kent State Univ, Inst Liquid Crystal, Kent, OH 44242 USA
[3] Azimuth Corp, Dayton, OH 45431 USA
[4] Alpha Micron Inc, Kent, OH 44242 USA
关键词
PHOTOCHROMIC FULGIDE; PHOTOISOMERIZATION; PITCH; SWITCH; FILMS;
D O I
10.1002/adma.201003577
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A photoinvertible chiral molecule allows for wide-range tuning encompassing the entirety of the optical range. UV light inverts the handedness of the cholesteric liquid-crystal (CLC) helix, which yields color tuning of the reflection notch. After the light is removed, the material quickly relaxes back to the original conformation. The optical properties of the CLC during tuning/inversion are correlated to the mesomorphic behavior of the mixture.
引用
收藏
页码:1389 / 1392
页数:4
相关论文
共 32 条
[1]   SENSITIVITY OF CHOLESTERIC FILMS TO ULTRAVIOLET EXPOSURE [J].
ADAMS, J ;
HAAS, W .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1971, 118 (12) :2026-&
[2]   Light induced effects in cholesteric mixtures with a photosensitive nexatic host [J].
Chanishvili, A ;
Chilaya, G ;
Petriashvili, G ;
Sikharulidze, D .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2004, 409 :209-218
[3]   Rotational reorganization of doped cholesteric liquid crystalline films [J].
Eelkema, Rienk ;
Pollard, Michael M. ;
Katsonis, Nathalie ;
Vicario, Javier ;
Broer, Dirk J. ;
Feringa, Ben L. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (44) :14397-14407
[4]   Reversible full-range color control of a cholesteric liquid-crystalline film by using a molecular motor [J].
Eelkema, Rienk ;
Feringa, Ben L. .
CHEMISTRY-AN ASIAN JOURNAL, 2006, 1 (03) :367-369
[5]   CHIROPTICAL MOLECULAR SWITCH [J].
FERINGA, BL ;
JAGER, WF ;
DELANGE, B ;
MEIJER, EW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (14) :5468-5470
[6]   CHIROPTICAL SWITCHING BETWEEN LIQUID-CRYSTALLINE PHASES [J].
FERINGA, BL ;
HUCK, NPM ;
VANDOREN, HA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (39) :9929-9930
[7]   INTERACTION BETWEEN UV RADIATION AND CHOLESTERIC LIQUID CRYSTALS [J].
HAAS, W ;
ADAMS, J ;
WYSOCKI, J .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1969, 7 :371-&
[8]   Wide temperature range azobenzene nematic and smectic LC materials [J].
Hrozhyk, U. ;
Serak, S. ;
Tabiryan, N. ;
Bunning, T. J. .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2006, 454 :235-245
[9]   Optical tuning of the reflection of cholesterics doped with azobenzene liquid crystals [J].
Hrozhyk, Uladzimir A. ;
Serak, Svetlana V. ;
Tabiryan, Nelson V. ;
Bunning, Timothy J. .
ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (11) :1735-1742
[10]   Phototunable reflection notches of cholesteric liquid crystals [J].
Hrozhyk, Uladzimir A. ;
Serak, Svetlana V. ;
Tabiryan, Nelson V. ;
Bunnin, Timothy J. .
JOURNAL OF APPLIED PHYSICS, 2008, 104 (06)