Inkjet printing of CH3NH3PbI3 on a mesoscopic TiO2 film for highly efficient perovskite solar cells

被引：207

作者：

Li, Shao-Gang ^{[1
]}

Jiang, Ke-Jian ^{[1
]}

Su, Mei-Ju ^{[1
,2
]}

Cui, Xue-Ping ^{[1
,2
]}

Huang, Jin-Hua ^{[1
]}

Zhang, Qian-Qian ^{[1
,2
]}

Zhou, Xue-Qin ^{[2
]}

Yang, Lian-Min ^{[1
]}

Song, Yan-Lin ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Key Lab Green Printing, Beijing 100190, Peoples R China

[2] Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300072, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2015年 / 3卷 / 17期

关键词：

TEMPERATURE; INTERFACE; LENGTHS;

D O I：

10.1039/c4ta05675b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An inkjet printing technique is successfully used to deposit a perovskite CH3NH3PbI3 layer on a mesoscopic TiO2 film. With combined optimization of the table temperature and the ink composition, a flat and uniform perovskite layer is realized on the TiO2 film, and the corresponding photovoltaic device exhibits a high efficiency of 12.3% with an average value of 11.2% under AM 1.5G conditions. The current work demonstrates that the inkjet printing method is environmentally benign and cost-effective with reduced waste of the toxic Pb-containing materials encountered inevitably in the existing techniques during the device preparation.

引用

页码：9092 / 9097

页数：6

共 31 条

[1] Low-temperature processed meso-superstructured to thin-film perovskite solar cells
Ball, James M.
Lee, Michael M.
Hey, Andrew
Snaith, Henry J.
[J]. ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (06) : 1739 - 1743
[2] Efficient planar heterojunction mixed-halide perovskite solar cells deposited via spray-deposition
Barrows, Alexander T.
Pearson, Andrew J.
Kwak, Chan Kyu
Dunbar, Alan D. F.
Buckley, Alastair R.
Lidzey, David G.
[J]. ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (09) : 2944 - 2950
[3] Sequential deposition as a route to high-performance perovskite-sensitized solar cells
Burschka, Julian
Pellet, Norman
Moon, Soo-Jin
Humphry-Baker, Robin
Gao, Peng
Nazeeruddin, Mohammad K.
Graetzel, Michael
[J]. NATURE, 2013, 499 (7458) : 316 - +
[4] Efficient and Uniform Planar-Type Perovskite Solar Cells by Simple Sequential Vacuum Deposition
Chen, Chang-Wen
Kang, Hao-Wei
Hsiao, Sheng-Yi
Yang, Po-Fan
Chiang, Kai-Ming
Lin, Hao-Wu
[J]. ADVANCED MATERIALS, 2014, 26 (38) : 6647 - 6652
[5] Planar Heterojunction Perovskite Solar Cells via Vapor-Assisted Solution Process
Chen, Qi
Zhou, Huanping
Hong, Ziruo
Luo, Song
Duan, Hsin-Sheng
Wang, Hsin-Hua
Liu, Yongsheng
Li, Gang
Yang, Yang
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (02) : 622 - 625
[6] Perovskite-Based Hybrid Solar Cells Exceeding 10% Efficiency with High Reproducibility Using a Thin Film Sandwich Approach
Conings, Bert
Baeten, Linny
De Dobbelaere, Christopher
D'Haen, Jan
Manca, Jean
Boyen, Hans-Gerd
[J]. ADVANCED MATERIALS, 2014, 26 (13) : 2041 - 2046
[7] Solution Deposition-Conversion for Planar Heterojunction Mixed Halide Perovskite Solar Cells
Docampo, Pablo
Hanusch, Fabian C.
Stranks, Samuel D.
Doeblinger, Markus
Feckl, Johann M.
Ehrensperger, Martin
Minar, Norma K.
Johnston, Michael B.
Snaith, Henry J.
Bein, Thomas
[J]. ADVANCED ENERGY MATERIALS, 2014, 4 (14)
[8] Effect of Annealing Temperature on Film Morphology of Organic-Inorganic Hybrid Pervoskite Solid-State Solar Cells
Dualeh, Amalie
Tetreault, Nicolas
Moehl, Thomas
Gao, Peng
Nazeeruddin, Mohammad Khaja
Graetzel, Michael
[J]. ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (21) : 3250 - 3258
[9] Mesoscopic CH3NH3PbI3/TiO2 Heterojunction Solar Cells
Etgar, Lioz
Gao, Peng
Xue, Zhaosheng
Peng, Qin
Chandiran, Aravind Kumar
Liu, Bin
Nazeeruddin, Md. K.
Graetzel, Michael
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (42) : 17396 - 17399
[10] Heo JH, 2013, NAT PHOTONICS, V7, P487, DOI [10.1038/nphoton.2013.80, 10.1038/NPHOTON.2013.80]

← 1 2 3 4 →