Photosensitized degradation of ethyl parathion pesticide in aqueous solution of anthracene modified photoactive dextran

被引:24
|
作者
Nowakowska, M [1 ]
Sterzel, M [1 ]
Zapotoczny, S [1 ]
Kot, E [1 ]
机构
[1] Jagiellonian Univ, Dept Chem, PL-30060 Krakow, Poland
关键词
polymeric photosensitizer; photodegradation; pesticide; parathion; photoinduced electron transfer;
D O I
10.1016/j.apcatb.2004.10.002
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The photosensitized oxidation of parathion-ethyl (PTE) pesticide in the aqueous solution of anthracene substituted dextran (DXA) was investigated. The phototransformation of PTE was found to be significantly enhanced in the presence of DXA. The suggested mechanisms of reactions involve photoinduced electron transfer process as a primary photophysical step. DXA polymer plays a role of environmentally friendly photosensitizer since after the reaction it undergoes decomposition. (c) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 8
页数:8
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