Synthesis and complexation properties of poly(ethylene glycol)-linked mono- and bis-dioxocyclams

被引：33

作者：

Puntener, K ^{[1
]}

Hellman, MD ^{[1
]}

Kuester, E ^{[1
]}

Hegedus, LS ^{[1
]}

机构：

[1] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2000年 / 65卷 / 24期

关键词：

D O I：

10.1021/jo001095q

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Both tri- and tetra(ethylene glycol) linked bis-chromium carbene complexes have been synthesized. These carbene complexes were photolyzed with N-protected imidazolines to give protected azapenams. These were transformed into polyether-linked basket dioxacyclams 4a,b and bis-dioxocyclams 5a,b. These compounds have-cavities for the complexation of both "hard" and "soft" metal ions.;The complexes of Ni, Ba, and Gd were synthesized.

引用

页码：8301 / 8306

页数：6

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