Ligand exchange and alkyl abstraction involving (perfluoroaryl)boranes and -alanes with aluminum and gallium alkyls

被引：129

作者：

Klosin, J ^{[1
]}

Roof, GR

Chen, EYX

Abboud, KA

机构：

[1] Dow Chem Co USA, Catalysis Lab, Midland, MI 48674 USA

[2] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 23期

关键词：

D O I：

10.1021/om000573k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction between M(C6F5)(3) (M = B, Al) and AlR3 in hydrocarbons leads to facile aryl/alkyl group exchange and formation of aluminum dimers, while reaction of(perfluoroaryl)boranes B(C6F5)(3) and B(C12F9)(3) with AlR3 (R = Me, Et, octyl) or GaMe3 in ether solvents produces alumocenium or gallocenium berates. Neutral aluminum dimers and cationic alumocenium species have been found to be very effective as catalyst activators in ethylene/1-octene copolymerization.

引用

页码：4684 / 4686

页数：3

共 43 条

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