Synthesis of poly(spiropyran)s by polycondensation and their photoisomerization behaviors

被引:13
作者
Kadokawa, Jun-ichi [1 ]
Tanaka, Yuhki [1 ]
Yamashita, Yoritake [1 ]
Yamamoto, Kazuya [1 ]
机构
[1] Kagoshima Univ, Grad Sch Sci & Engn, Kagoshima 8900065, Japan
关键词
Photochromism; Photoisomerization; Polycondensation; Spiropyran; SPIROPYRAN; SYSTEMS; POLYMERIZATION; COPOLYMERS; POLYMERS;
D O I
10.1016/j.eurpolymj.2011.12.008
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Poly(spiropyran)s were synthesized by polycondensation of a bis(indoline) monomer with bis(o-positioned formyl and hydroxy)-substituted aromatic monomers in alcoholic solvents. The structures of the products and their molecular weights were determined by the H-1 NMR and GPC measurements, respectively. Furthermore, photoisomerization behaviors of the poly(spiropyran)s were analyzed by the UV-Vis and H-1 NMR measurements of their solutions in dichloromethane upon the UV and visible light irradiations. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:549 / 559
页数:11
相关论文
共 19 条
  • [1] Multiresponsive Spiropyran-Based Copolymers Synthesized by Atom Transfer Radical Polymerization
    Achilleos, Demetra S.
    Vamvakaki, Maria
    [J]. MACROMOLECULES, 2010, 43 (17) : 7073 - 7081
  • [2] All-photonic molecular half-adder
    Andreasson, Joakim
    Straight, Stephen D.
    Kodis, Gerdenis
    Park, Choong-Do
    Hambourger, Michael
    Gervaldo, Miguel
    Albinsson, Bo
    Moore, Thomas A.
    Moore, Ana L.
    Gust, Devens
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (50) : 16259 - 16265
  • [3] Opening a spiropyran ring by way of an exciplex intermediate
    Benniston, Andrew C.
    Harriman, Anthony
    Howell, Sarah L.
    Li, Peiyi
    Lydon, Donocadh P.
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (03) : 888 - 897
  • [4] A general strategy for the facile synthesis of 2,7-dibromo-9-heterofluorenes
    Chen, RF
    Fan, QL
    Zheng, C
    Huang, W
    [J]. ORGANIC LETTERS, 2006, 8 (02) : 203 - 205
  • [5] Fiesel R, 1998, ACTA POLYM, V49, P445, DOI 10.1002/(SICI)1521-4044(199808)49:8<445::AID-APOL445>3.3.CO
  • [6] 2-D
  • [7] Photoresponsive polypeptides, photochromic and conformational behavior of spiropyran-containing poly(L-glutamate)s under acid conditions
    Fissi, A
    Pieroni, O
    Angelini, N
    Lenci, F
    [J]. MACROMOLECULES, 1999, 32 (21) : 7116 - 7121
  • [8] 7-trifluoromethylquinoline-functionalized luminescent photochromic spiropyran with the stable merocyanine species both in solution and in the solid state
    Guo, XF
    Zhou, YC
    Zhang, DQ
    Bing, Y
    Liu, ZL
    Liu, CM
    Lu, ZL
    Huang, YH
    Zhu, DB
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (25) : 8924 - 8931
  • [9] Reversible photoregulation of the electrical conductivity of spiropyran-doped polyaniline for information recording and nondestructive processing
    Guo, XF
    Zhang, D
    Gui, Y
    Wax, MX
    Li, JC
    Liu, YQ
    Zhu, DB
    [J]. ADVANCED MATERIALS, 2004, 16 (07) : 636 - +
  • [10] IRIE M, 1990, ADV POLYM SCI, V94, P27