Isothermal section of ternary Sn-Zn-Ni phase equilibria at 250 °C

被引:10
作者
Chen, Sinn-wen [1 ]
Hsu, Chia-ming [1 ]
Chou, Chin-yi [1 ]
Hsu, Che-wei [1 ]
机构
[1] Natl Tsing Hua Univ, Dept Chem Engn, Hsinchu, Taiwan
关键词
Pb-free solder; phase equilibria; Sn-Zn; Ni; INTERFACIAL REACTIONS; SOLDER; ELECTROMIGRATION; SN-8ZN-3BI;
D O I
10.1016/S1002-0071(12)60074-4
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Ternary Sn-Zn-Ni alloys were prepared and equilibrated at 250 degrees C for 4-15 weeks. The phases formed in these equilibrated alloys were determined experimentally. The isothermal section of Sn-Zn-Ni system was constructed, based on the phase diagrams of the three constituent binary systems and the ternary phase equilibria data, determined in this study and referenced in literatures. 12 single-phase regions were identified in the Sn-Zn-Ni ternary system at 250 degrees C, including the three ternary compounds, delta, tau(1) and tau(2). There were 13 ternary phase regions and 23 binary phase regions in the 250 degrees C Sn-Zn-Ni isothermal section. The solubility of Zn in the binary Sn-Ni compounds is significant, and is 15.1% (mole fraction) in the Ni(3)Sn phase.
引用
收藏
页码:386 / 391
页数:6
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