Enhanced Mechanical Properties, Corrosion Behavior and Bioactivity of Ti-based Bulk Metallic Glasses with Minor Addition Elements

被引：14

作者：

Qin, Feng-Xiang ^{[1
,3
]}

Zhou, Yang ^{[1
]}

Ji, Chuan ^{[1
]}

Dan, Zhen-Hua ^{[2
]}

Xie, Guo-Qiang ^{[3
]}

Yang, Sen ^{[1
]}

机构：

[1] Nanjing Univ Sci & Technol, Sch Mat Sci & Engn, Nanjing 210094, Jiangsu, Peoples R China

[2] Nanjing TECH Univ, Coll Mat Sci & Engn, Nanjing 210009, Jiangsu, Peoples R China

[3] Tohoku Univ, Inst Mat Res, Sendai, Miyagi 9808577, Japan

来源：

ACTA METALLURGICA SINICA-ENGLISH LETTERS | 2016年 / 29卷 / 11期

关键词：

Bulk metallic glass; Microstructure; Alloy design; Corrosion; Mechanical behavior; Biocompatibility; CALCIUM-PHOSPHATE; FORMING ABILITY; ALLOY; DEFORMATION; COMPOSITE; LAYER; RESISTANCE;

D O I：

10.1007/s40195-016-0468-0

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

In this research, corrosion behavior, mechanical properties and bioactivity of Ti-Zr-Cu-Pd-Sn bulk metallic glasses with minor addition of Au, Pt, Nb or Ta elements were investigated. The results revealed that minor additions of the elements were beneficial to enhancing mechanical properties and corrosion resistance of Ti-based bulk metallic glasses. Minor addition of the element (especially with Nb and Ta addition) results in the improvement in plastic deformation ability due to the existing of nanoparticles with a size smaller than 10 nm in glassy matrix, inhibiting the deformation of the shear bonds. Enrichments of Ti and Zr elements in oxide layer were responsible for high corrosion resistance. The bioactivity of Ti-based bulk metallic glasses was also investigated. The best combination of large plastic deformation ability, good corrosion resistance and bioactivity in Ti40Zr10Cu33Pd14Sn2Ta1 BMG was obtained.

引用

页码：1011 / 1018

页数：8

共 40 条

[1] Effects of Zr Content on the Microstructures and Tensile Properties of Ti-3Al-8V-6Cr-4Mo-xZr Alloys [J].

Ba, Hong-Bo ;

Dong, Li-Min ;

Zhang, Zhi-Qiang ;

Xu, Dong-Sheng ;

Yang, Rui .

ACTA METALLURGICA SINICA-ENGLISH LETTERS, 2016, 29 (08) :722-726

[2] Effects of Nitrogen on the Glass Formation and Mechanical Properties of a Ti-Based Metallic Glass [J].

Cao, Di ;

Wu, Yuan ;

Wang, Hui ;

Liu, Xiong-Jun ;

Lu, Z. P. .

ACTA METALLURGICA SINICA-ENGLISH LETTERS, 2016, 29 (02) :173-180

[3] Synthesis and characterization of particulate reinforced Zr57Nb5Al10Cu15.4Ni12.6 bulk metallic glass composites [J].

Choi-Yim, H ;

Busch, R ;

Köster, U ;

Johnson, WL .

ACTA MATERIALIA, 1999, 47 (08) :2455-2462

[4] Effect of crystallization on the mechanical properties of Zr56.7CU15.3Ni12.5Nb5.0Al10.0Y0.5bulk amorphous alloy [J].

Das, K ;

Bandyopadhyay, A ;

Gupta, YM .

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2005, 394 (1-2) :302-311

[5] Metallic glass matrix composite with precipitated ductile reinforcement [J].

Fan, C ;

Ott, RT ;

Hufnagel, TC .

APPLIED PHYSICS LETTERS, 2002, 81 (06) :1020-1022

[6] Carbonate apatite coating on titanium induced rapidly by precalcification [J].

Feng, B ;

Chen, JY ;

Qi, SK ;

He, L ;

Zhao, JZ ;

Zhang, XD .

BIOMATERIALS, 2002, 23 (01) :173-179

[7] Novel Ti-base nanostructure-dendrite composite with enhanced plasticity [J].

He, G ;

Eckert, J ;

Löser, W ;

Schultz, L .

NATURE MATERIALS, 2003, 2 (01) :33-37

[8] INNOVATIVE MATERIALS PROCESSING STRATEGIES - A BIOMIMETIC APPROACH [J].

HEUER, AH ;

FINK, DJ ;

LARAIA, VJ ;

ARIAS, JL ;

CALVERT, PD ;

KENDALL, K ;

MESSING, GL ;

BLACKWELL, J ;

RIEKE, PC ;

THOMPSON, DH ;

WHEELER, AP ;

VEIS, A ;

CAPLAN, AI .

SCIENCE, 1992, 255 (5048) :1098-1105

[9] Short- and medium-range order in (Zr70Cu20Ni10)90-xTaxAl10 bulk amorphous alloys -: art. no. 014203 [J].

Hufnagel, TC ;

Brennan, S .

PHYSICAL REVIEW B, 2003, 67 (01)

[10] Stabilization of metallic supercooled liquid and bulk amorphous alloys [J].

Inoue, A .

ACTA MATERIALIA, 2000, 48 (01) :279-306

← 1 2 3 4 →