Densities and viscosities of binary mixtures of m-cresol with some chlorohydrocarbons

被引:14
作者
Prasad, TEV [1 ]
Phanibhushan, A
Prasad, DHL
机构
[1] Indian Inst Chem Technol, Chem Engn Lab, Hyderabad 500007, Andhra Pradesh, India
[2] Sri Venkateswara Univ, Coll Engn, Dept Chem Engn, Tirupati 517502, Andhra Pradesh, India
关键词
excess volume; viscosity deviation; Gibbs energy for activation of flow; m-cresol; chlorohydrocarbons; binary mixtures;
D O I
10.1007/s10953-005-8017-x
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Densities and viscosities of the binary mixtures of m-cresol with 1,2-dichloroethane, 1,1,1-trichloroethane,1,1,2,2-tetrachloroethane and tetrachloroethylene were measured at 303.15, 313.15 and 323.15K. The measured results are used to compute the excess volumes (V-E), deviations in viscosity (Delta(eta)) and excess Gibbs energy for activation of flow (Delta G(E)). The excess volumes, deviations in viscosity, and Gibbs energies for activation of flow are fitted to a polynomial-type equation suggested by Scharlin et al. [J. Chem. Thermodyn. 34, 927 (2002)] and are discussed in general terms.
引用
收藏
页码:1263 / 1272
页数:10
相关论文
共 5 条
[1]   MOLAR EXCESS VOLUMES AND MOLAR EXCESS-ENTHALPIES OF SOME TERNARY MIXTURES OF NONELECTROLYTES [J].
DAHIYA, HP ;
SINGH, PP ;
DAGAR, S .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1988, 33 (04) :448-450
[2]   Densities and viscosities of the binary mixtures of chloroethylenes with some aliphatic alcohols [J].
Prasad, TEV ;
Mythili, R ;
Nirmala, GS ;
Prasad, DHL .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2002, 47 (01) :68-71
[3]  
Riddick JA., 1986, Organic Solvents. Physical Properties and Methods of Purification, V4
[4]   Volumetric properties of binary mixtures of N,N-dimethylformamide with water or water-d2 at temperatures from 277.13 K to 318.15 K [J].
Scharlin, P ;
Steinby, K ;
Domanska, U .
JOURNAL OF CHEMICAL THERMODYNAMICS, 2002, 34 (06) :927-957
[5]   Densities and viscosities of binary liquid mixtures of anisole or methyl tert-butyl ether with benzene, chlorobenzene, benzonitrile, and nitrobenzene [J].
Viswanathan, S ;
Rao, MA ;
Prasad, DHL .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2000, 45 (05) :764-770