Preorganized Frustrated Lewis Pairs

被引：197

作者：

Bertini, Federica ^{[1
]}

Lyaskoyskyy, Volodymyr ^{[1
]}

Timmer, Brian J. J. ^{[1
]}

de Kanter, Frans J. J. ^{[1
]}

Lutz, Martin ^{[2
]}

Ehlers, Andreas W. ^{[1
]}

Slootweg, J. Chris ^{[1
]}

Lammertsma, Koop ^{[1
]}

机构：

[1] Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands

[2] Univ Utrecht, Bijvoet Ctr Biomol Res Crystal & Struct Chem, NL-3584 CH Utrecht, Netherlands

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 01期

关键词：

FREE CATALYTIC-HYDROGENATION; HETEROLYTIC DIHYDROGEN ACTIVATION; ADDITION-REACTIONS; H-2; ACTIVATION; REACTIVITY; BORANE; MECHANISM; IMINES; CO2; PHOSPHINES;

D O I：

10.1021/ja210214r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Geminal frustrated Lewis pairs (FLPs) are expected to exhibit increased reactivity when the donor and acceptor sites are perfectly aligned. This is shown for reactions of the nonfluorinated FLP tBu(2)PCH(2)BPh(2) with H-2, CO2, and isocyanates and supported computationally.

引用

页码：201 / 204

页数：4

共 50 条

[21] Intramolecular cooperativity in frustrated Lewis pairs
Koerte, Leif A.
Blomeyer, Sebastian
Heidemeyer, Shari
Mix, Andreas
Neumann, Beate
Mitzel, Norbert W.
CHEMICAL COMMUNICATIONS, 2016, 52 (64) : 9949 - 9952
[22] Transition Metal Frustrated Lewis Pairs
Flynn, Stephanie R.
Wass, Duncan F.
ACS CATALYSIS, 2013, 3 (11): : 2574 - 2581
[23] Broadening the synthetic organic applications of Frustrated Lewis Pairs
Arkhipenko, Sergey
Whiting, Andrew
ARKIVOC, 2017, : 26 - 40
[24] Intramolecular Frustrated Lewis Pairs: Formation and Chemical Features
Kehr, Gerald
Schwendemann, Sina
Erker, Gerhard
FRUSTRATED LEWIS PAIRS I: UNCOVERING AND UNDERSTANDING, 2013, 332 : 45 - 83
[25] Computational Design of Frustrated Lewis Pairs as a Strategy for Activation and
Dagnaw, Wasihun Menberu
Mohammed, Ahmed M.
ACS OMEGA, 2023, : 8488 - 8496
[26] Deprotonation and Addition Reactions of Frustrated Lewis Pairs with Alkynes
Dureen, Meghan A.
Brown, Christopher C.
Stephan, Douglas W.
ORGANOMETALLICS, 2010, 29 (23) : 6594 - 6607
[27] Heterolytic Cleavage of H2 by Frustrated B/N Lewis Pairs
Jiang, Chunfang
Blacque, Olivier
Fox, Thomas
Berke, Heinz
ORGANOMETALLICS, 2011, 30 (08) : 2117 - 2124
[28] Exploring the Reactivity of Carbon(0)/Borane-Based Frustrated Lewis Pairs
Alcarazo, Manuel
Gomez, Catherine
Holle, Sigrid
Goddard, Richard
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (33) : 5788 - 5791
[29] Frustrated Lewis Pairs: A New Strategy for Metal-Free Catalytic Hydrogenation
Wang, Pingan
Sun, Xiaoli
Gao, Peng
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2011, 31 (09) : 1369 - 1376
[30] "Inverse" Frustrated Lewis Pairs - Activation of Dihydrogen with Organosuperbases and Moderate to Weak Lewis Acids
Mummadi, Suresh
Unruh, Daniel K.
Zhao, Jiyang
Li, Shuhua
Krempner, Clemens
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (10) : 3286 - 3289

← 1 2 3 4 5 →