Crystal growth and spectroscopic investigations of Dy: YAlO 3 and Dy,Tm: YAlO 3 crystals for-3?m laser application

Dy3+:YAP and Dy3+,Tm3+:YAP single crystals have been successfully obtained by Czochralski (CZ) method aiming for ∼3 μm emission. The optical absorption and emission features of both crystals were studied in detail. A narrow and weak absorption band around 800 nm as well as the up-conversion emissions under the excitation of 802 nm in Dy3+:YAP crystal, along with a weak ∼3 μm emission were observed, indicating that Dy3+:YAP crystal was not suitable for direct pumping under 800 nm excitation. Tm3+ ion was introduced as a sensitizer for enhancing ∼3 μm emission. It was found that co-doping with Tm3+ greatly improved the absorption capacity around 800 nm. And thus an enhanced ∼2.84 μm emission was realized in Dy3+,Tm3+:YAP crystal under 795 nm excitation. The energy transfer mechanisms between Tm3+ and Dy3+ ions were discussed, and high microscopic energy transfer constants between Tm3+ and Dy3+ ions were obtained, proving that Tm3+ ion could act as an effective sensitizer for Dy3+ ion in YAP crystal. Following the obtained spectroscopic results, Dy3+,Tm3+:YAP crystal could be a promising medium for ∼3 μm laser operation under 795 nm laser diode for practical applications. © 2020 Elsevier B.V.