Interfacial Synthesis of Two-Dimensional Dendritic Platinum Nanoparticles Using Oleic Acid-in-Water Emulsion

被引:28
作者
Jung, Eui-Geun [1 ]
Shin, Yonghee [1 ]
Lee, Minzae [2 ]
Yo, Jongheop [2 ]
Kang, Taewook [1 ]
机构
[1] Sogang Univ, Dept Chem & Biomol Engn, Seoul 121742, South Korea
[2] Seoul Natl Univ, Inst Chem Proc, Sch Chem & Biol Engn, Seoul 151742, South Korea
基金
新加坡国家研究基金会;
关键词
interfacial synthesis; dendritic platinum nanoparticle; two-dimensional structure; oil-in-water emulsion; electrocatalytic activity; ATOMIC LAYER DEPOSITION; TRIBLOCK COPOLYMERS; MEDIATED SYNTHESIS; FACILE SYNTHESIS; NANOCRYSTALS; GROWTH; SIZE;
D O I
10.1021/acsami.5b02433
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Here we propose facile and scalable synthesis of two-dimensional (2D) dendritic platinum nanoparticle at room temperature by exploiting an oil-in-water emulsion. The interfacial synthesis selectively provides platinum nanoparticle with 2D structure in high yield by controlling key reactants such as the amount of oleic acid and the concentration of block copolymer. Electrocatalytic activity of 2D dendritic platinum nanoparticle for oxygen reduction and methanol oxidation reaction is also examined.
引用
收藏
页码:10666 / 10670
页数:5
相关论文
共 29 条
[21]   Synthesis of porous platinum nanoparticles [J].
Teng, XW ;
Liang, XY ;
Maksimuk, S ;
Yang, H .
SMALL, 2006, 2 (02) :249-253
[22]   Synthesis of tetrahexahedral platinum nanocrystals with high-index facets and high electro-oxidation activity [J].
Tian, Na ;
Zhou, Zhi-You ;
Sun, Shi-Gang ;
Ding, Yong ;
Wang, Zhong Lin .
SCIENCE, 2007, 316 (5825) :732-735
[23]   Facile Synthesis of Three-Dimensional Dendritic Platinum Nanoelectrocatalyst [J].
Wang, Liang ;
Yamauchi, Yusuke .
CHEMISTRY OF MATERIALS, 2009, 21 (15) :3562-3569
[24]   Block Copolymer Mediated Synthesis of Dendritic Platinum Nanoparticles [J].
Wang, Liang ;
Yamauchi, Yusuke .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (26) :9152-+
[25]   High dispersion of platinum-ruthenium nanoparticles on the 3,4,9,10-perylene tetracarboxylic acid-functionalized carbon nanotubes for methanol electro-oxidation [J].
Wu, Bohua ;
Hu, Dan ;
Kuang, Yinjie ;
Yu, Yaming ;
Zhang, Xiaohua ;
Chen, Jinhua .
CHEMICAL COMMUNICATIONS, 2011, 47 (18) :5253-5255
[26]   Ultrathin and Ultralong Single-Crystal Platinum Nanowire Assemblies with Highly Stable Electrocatalytic Activity [J].
Xia, Bao Yu ;
Wu, Hao Bin ;
Yan, Ya ;
Lou, Xiong Wen ;
Wang, Xin .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (25) :9480-9485
[27]   Vapor infiltration of a reducing agent for facile synthesis of mesoporous Pt and Pt-based alloys and its application for the preparation of mesoporous Pt microrods in anodic porous membranes [J].
Yamauchi, Yusuke ;
Takai, Azusa ;
Komatsu, Masaki ;
Sawada, Makoto ;
Ohsuna, Tetsu ;
Kuroda, Kazuyuki .
CHEMISTRY OF MATERIALS, 2008, 20 (03) :1004-1011
[28]   Platinum Concave Nanocubes with High-Index Facets and Their Enhanced Activity for Oxygen Reduction Reaction [J].
Yu, Taekyung ;
Kim, Do Youb ;
Zhang, Hui ;
Xia, Younan .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (12) :2773-2777
[29]   Facile synthesis of morphology-controlled platinum nanocrystals [J].
Zhong, Xinhua ;
Feng, Yaoyu ;
Lieberwirth, Ingo ;
Knoll, Wolfgang .
CHEMISTRY OF MATERIALS, 2006, 18 (10) :2468-2471