Thermodynamics of plutonium(iii) and curium(iii) complexation with a N-donor ligand

被引：4

作者：

Miguirditchian, Manuel ^{[1
]}

Guillaumont, Dominique ^{[1
]}

Saint-Maxent, Audrey ^{[1
]}

Moisy, Philippe ^{[1
]}

Guillaneux, Denis ^{[2
]}

Madic, Charles ^{[1
]}

机构：

[1] CEA, Res Dept Min & Fuel Recycling Proc, Nucl Energy Div, BP17171, F-30207 Bagnols Sur Ceze, France

[2] CEA, DPC, DANS, Nucl Energy Div, F-91191 Gif Sur Yvette, France

来源：

DALTON TRANSACTIONS | 2019年 / 48卷 / 03期

关键词：

SOLVENT-EXTRACTION; AMERICIUM(III); EUROPIUM(III); LUMINESCENCE; LANTHANIDE(III); COMPENSATION; SOLVATION; CATIONS;

D O I：

10.1039/c8dt04671a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexation of Pu(III) and Cm(III) with a soft N-donor ligand was investigated using the van't Hoff method, microcalorimetry and DFT calculations. The studies revealed that the strength of the actinide-ligand bond as given by the enthalpic contribution drastically decreases on going from Pu(III) to Cm(III), while the complex stability remains nearly constant.

引用

页码：839 / 842

页数：4

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