Intermolecular interactions of fenvalerate with petroleum sulfoxides and sulfones

被引:0
|
作者
Kolyadina, OA [1 ]
Mikhailenko, OI [1 ]
Murinov, YI [1 ]
机构
[1] Russian Acad Sci, Inst Inorgan Chem, Ufa Sci Ctr, Bashkortostan 450054, Russia
来源
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY | 2001年 / 75卷 / 07期
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中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Gas-liquid chromatography and viscometry were used to study the intermolecular interaction of fenvalerate with petroleum sulfoxides and sulfones in the temperature range from 50 to 65 degreesC. The calculated thermodynamic parameters of the interaction were presented as functions of the composition. The highest deviations from additivity were observed at the equimolar ratios of the components. The coordination centers of interacting molecules were detected by H-1 NMR spectroscopy.
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页码:1197 / 1200
页数:4
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