Organic-inorganic hybrid polyoxometalates: Efficient, heterogeneous and reusable catalysts for solvent-free synthesis of azlactones

被引：42
作者：
Rostami, Mahbubeh [1 ]
Khosropour, Ahmadreza [1 ]
Mirkhani, Valiollah [1 ]
Moghadam, Majid [1 ]
Tangestaninejad, Shahram [1 ]
Mohammadpoor-Baltork, Iraj [1 ]
机构：
[1] Univ Isfahan, Catalysis Div, Dept Chem, Esfahan 8174673441, Iran
来源：
APPLIED CATALYSIS A-GENERAL | 2011年 / 397卷 / 1-2期
关键词：
Hybrid polyoxometalate; Heterogeneous catalysts; Azlactone; Solvent-free; IONIC LIQUID; 12-PHOSPHOTUNGSTIC ACID; 4-ARYLIDENE-2-PHENYL-5(4H)-OXAZOLONES; ACETATE; ANION; SALT;
D O I：
10.1016/j.apcata.2011.02.004
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Two organic-inorganic hybrid polyoxometalates, consist of 1-butyl-3-methylimidazolium salts of (W10O32)(4-) and (RW12O40)(3-) polyanions were prepared and characterized by thermal analysis, X-ray diffraction, FT-IR, diffuse reflectance UV-Vis spectroscopic methods and nitrogen absorption-desorption determination (BET). These heterogeneous catalysts were used for synthesis of azlactones by the reaction of aldehydes with hippuric acid and acetic anhydride under solvent-free conditions. These catalysts were reused several times without loss of their activities. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码：27 / 34
页数：8
相关论文
共 51 条
  • [11] Etschenberg E., 1980, Ger. Pat., Patent No. 904512
  • [12] FRED M, 1988, SYNTHESIS-STUTTGART, P1659
  • [13] 5(4H)-oxazolones .10. Acid and base effects on the translactonization reaction of 4-(2-oxa-alkylidene)-5(4H)-oxazolones: New synthesis of 5-alkylidene-3-benzoylamino-2(5H)-furanones
    Gelmi, ML
    Clerici, F
    Melis, A
    [J]. TETRAHEDRON, 1997, 53 (05) : 1843 - 1854
  • [14] Ring opening with kinetic resolution of azlactones by Ti-TADDOLates
    Gottwald, K
    Seebach, D
    [J]. TETRAHEDRON, 1999, 55 (03) : 723 - 738
  • [15] Self-Process-Programmed Structural Diversity in Supramolecular Assembly Based on Polyoxometalate Anion and Halogensubstituted Bipyridine Cation
    Han, Zhangang
    Gao, Yuanzhe
    Zhai, Xueliang
    Peng, Jun
    Tian, Aixiang
    Zhao, Yulong
    Hu, Changwen
    [J]. CRYSTAL GROWTH & DESIGN, 2009, 9 (02) : 1225 - 1234
  • [16] Photochromism in composite and hybrid materials based on transition-metal oxides and polyoxometalates
    He, Tao
    Yao, Jiannian
    [J]. PROGRESS IN MATERIALS SCIENCE, 2006, 51 (06) : 810 - 879
  • [17] He Z.Q., 2001, J CHEM RES APPL, V13, P253
  • [18] Ichi S., 1999, SPECTROSC LETT, V32, P553
  • [19] Ionic conductivity, infrared and Raman spectroscopic studies of 1-methyl-3-propylimidazolium iodide ionic liquid with added iodine
    Jerman, I.
    Jovanovski, V.
    Vuk, A. Surca
    Hocevar, S. B.
    Gaberscek, M.
    Jesih, A.
    Orel, B.
    [J]. ELECTROCHIMICA ACTA, 2008, 53 (05) : 2281 - 2288
  • [20] Oxazolones: New tyrosinase inhibitors; synthesis and their structure-activity relationships
    Khan, Khalid Mohammed
    Mughal, Uzma Rasool
    Khan, Mahmud Tareq Hassan
    Zia-Ullah
    Perveen, Shahnaz
    Choudhary, Muhammad Iqbal
    [J]. BIOORGANIC & MEDICINAL CHEMISTRY, 2006, 14 (17) : 6027 - 6033
123456