An All-Phosphate and Zero-Strain Sodium-Ion Battery Based on Na3V2(PO4)3 Cathode, NaTi2(PO4)3 Anode, and Trimethyl Phosphate Electrolyte with Intrinsic Safety and Long Lifespan

被引：43
作者：
Jiang, Xiaoyu [1 ]
Zeng, Ziqi [1 ]
Xiao, Lifen [2 ]
Ai, Xinping [1 ]
Yang, Hanxi [1 ]
Cao, Yuliang [1 ]
机构：
[1] Wuhan Univ, Coll Chem & Mol Sci, Hubei Key Lab Elect Power Sources, Wuhan 430072, Hubei, Peoples R China
[2] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Hubei, Peoples R China
来源：
ACS APPLIED MATERIALS & INTERFACES | 2017年 / 9卷 / 50期
基金：
中国国家自然科学基金;
关键词：
phosphate; safety; zero-strain; sodium-ion batteries; energy storage; SUPERIOR ELECTROCHEMICAL PERFORMANCE; CYCLING STABILITY; SOLID-ELECTROLYTE; RATE CAPABILITY; GRAPHENE OXIDE; HIGH-POWER; LOW-COST; LITHIUM; COMPOSITE; INSERTION;
D O I：
10.1021/acsami.7b14946
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Development of intrinsically safe and long lifespan sodium-ion batteries,(SIBs) is urgently needed for large-scale energy storage applications. However, most of the currently developed SIBs suffer from insufficient cycle life and potential unsafety. Herein, we construct an all-phosphate sodium-ion battery (AP-SIB) using a Na3V2(PO4)(3) cathode, NaTi2(PO4)(3) anode, and nonflammable trimethyl phosphate (TMP) eleCtrolyte. The AP-SIB exhibits not only high safety, high rate performance, and ulttalong cycle life but' also zero-strain characteristics due to the inverse volume change of the phosphate "cathode and anode during charge and discharge cycles, offering a safer and cycle-stable M.:don technology for electric storage applications.
引用
收藏
页码：43733 / 43738
页数：6
相关论文
共 55 条
[1]   Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applications [J].
Cao, Yuliang ;
Xiao, Lifen ;
Sushko, Maria L. ;
Wang, Wei ;
Schwenzer, Birgit ;
Xiao, Jie ;
Nie, Zimin ;
Saraf, Laxmikant V. ;
Yang, Zhengguo ;
Liu, Jun .
NANO LETTERS, 2012, 12 (07) :3783-3787
[2]   Reversible Sodium Ion Insertion in Single Crystalline Manganese Oxide Nanowires with Long Cycle Life [J].
Cao, Yuliang ;
Xiao, Lifen ;
Wang, Wei ;
Choi, Daiwon ;
Nie, Zimin ;
Yu, Jianguo ;
Saraf, Laxmikant V. ;
Yang, Zhenguo ;
Liu, Jun .
ADVANCED MATERIALS, 2011, 23 (28) :3155-+
[3]   Electrochemical Profile of LiTi2(PO4)3 and NaTi2(PO4)3 in Lithium, Sodium or Mixed Ion Aqueous Solutions [J].
Chen, Long ;
Liu, Jingyuan ;
Guo, Zhaowei ;
Wang, Yonggang ;
Wang, Congxiao ;
Xia, Yongyao .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2016, 163 (06) :A904-A910
[4]   THE NASICON-TYPE TITANIUM PHOSPHATES LITI2(PO4)3, NATI2(PO4)3 AS ELECTRODE MATERIALS [J].
DELMAS, C ;
NADIRI, A ;
SOUBEYROUX, JL .
SOLID STATE IONICS, 1988, 28 :419-423
[5]   Flexible Aqueous Lithium-Ion Battery with High Safety and Large Volumetric Energy Density [J].
Dong, Xiaoli ;
Chen, Long ;
Su, Xiuli ;
Wang, Yonggang ;
Xia, Yongyao .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (26) :7474-7477
[6]   Environmentally-friendly aqueous Li (or Na)-ion battery with fast electrode kinetics and super-long life [J].
Dong, Xiaoli ;
Chen, Long ;
Liu, Jingyuan ;
Haller, Servane ;
Wang, Yonggang ;
Xia, Yongyao .
SCIENCE ADVANCES, 2016, 2 (01)
[7]   Recent Developments in Cathode Materials for Na Ion Batteries [J].
Fang Yong-Jin ;
Chen Zhong-Xue ;
Ai Xin-Ping ;
Yang Han-Xi ;
Cao Yu-Liang .
ACTA PHYSICO-CHIMICA SINICA, 2017, 33 (01) :211-241
[8]   Phosphate Framework Electrode Materials for Sodium Ion Batteries [J].
Fang, Yongjin ;
Zhang, Jiexin ;
Xiao, Lifen ;
Ai, Xinping ;
Cao, Yuliang ;
Yang, Hanxi .
ADVANCED SCIENCE, 2017, 4 (05)
[9]   3D Graphene Decorated NaTi2(PO4)3 Microspheres as a Superior High-Rate and Ultracycle-Stable Anode Material for Sodium Ion Batteries [J].
Fang, Yongjin ;
Xiao, Lifen ;
Qian, Jiangfeng ;
Cao, Yuliang ;
Ai, Xinping ;
Huang, Yunhui ;
Yang, Hanxi .
ADVANCED ENERGY MATERIALS, 2016, 6 (19)
[10]   Hierarchical Carbon Framework Wrapped Na3V2(PO4)3 as a Superior High-Rate and Extended Lifespan Cathode for Sodium-Ion Batteries [J].
Fang, Yongjin ;
Xiao, Lifen ;
Ai, Xinping ;
Cao, Yuliang ;
Yang, Hanxi .
ADVANCED MATERIALS, 2015, 27 (39) :5895-5900
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