Nickel-catalyzed carboxylation of aryl iodides with lithium formate through catalytic CO recycling

被引:16
作者
Wu, Ya-Nan [1 ]
Fu, Ming-Chen [1 ]
Shang, Rui [1 ,2 ]
Fu, Yao [1 ]
机构
[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, CAS Key Lab Urban Pollutant Convers, Anhui Prov Key Lab Biomass Clean Energy,iChEM, Hefei 230026, Peoples R China
[2] Univ Tokyo, Sch Sci, Dept Chem, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1130033, Japan
基金
中国国家自然科学基金; 中国博士后科学基金; 国家重点研发计划;
关键词
FORMIC-ACID; HYDROCARBOXYLATION; HALIDES; ALKYNES; CARBONYLATION; PD; HYDROXYCARBONYLATION; HYDROFORMYLATION; OLEFINS;
D O I
10.1039/d0cc01363c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A protocol for the Ni-catalyzed carboxylation of aryl iodides with formate has been developed with good functional group compatibility for the synthesis of a variety of aromatic carboxylic acids under mild conditions. The reaction tolerates other functionalities for cross-coupling, such as aryl bromide, aryl chloride, aryl tosylate, and aryl pinacol boronate. The reaction proceeds through a carbonylation process with in situ generated carbon monoxide in the presence of a catalytic amount of acetic anhydride and lithium formate, avoiding the use of gaseous CO. The strategy of CO recycling in catalytic amounts is critical for the success of the reaction.
引用
收藏
页码:4067 / 4069
页数:3
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