Refractory high entropy alloy with ductile intermetallic B2 matrix / hard bcc particles and exceptional strain hardening capacity

被引:38
作者
Yurchenko, Nikita [1 ]
Panina, Evgeniya [1 ]
Shaysultanov, Dmitry [1 ]
Zherebtsov, Sergey [1 ]
Stepanov, Nikita [1 ]
机构
[1] Belgorod Natl Res Univ, Lab Bulk Nanostruct Mat, Belgorod 308015, Russia
基金
俄罗斯科学基金会;
关键词
Refractory high entropy alloys; B2; phase; Structure; Mechanical properties; Deformation behavior; MECHANICAL-PROPERTIES; B2-TYPE COZR; TEMPERATURE; MICROSTRUCTURE; PRECIPITATION; BEHAVIOR; NANOPARTICLES; SUPERALLOYS; STABILITY; ADDITIONS;
D O I
10.1016/j.mtla.2021.101225
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this study, a new Nb30Mo30Hf20Co20 (at. %) refractory high entropy alloy (RHEA) comprising an intermetallic (Hf, Co)-rich B2 matrix and disordered (Nb, Mo)-rich bcc particles was introduced. The B2 matrix showed relatively high dislocation mobility, which, coupled with its continuity, allowed bridging and blunting of the cracks formed in the hard bcc particles during plastic deformation. The complex deformation behavior of the constitutive phases resulted in extraordinary high strain hardening capacity at 22-600 degrees C, exceeding single- and multi-phase RHEAs, together with the high strength. Our work endows new opportunities to develop high-performance alloys for high-temperature applications.
引用
收藏
页数:7
相关论文
共 51 条
[1]   Determination of the dislocation-based mechanism(s) responsible for the anomalous ductility of a class of B2 intermetallic alloys [J].
Agnew, S. R. ;
Ungar, T. .
40TH RISO INTERNATIONAL SYMPOSIUM ON MATERIALS SCIENCE: METAL MICROSTRUCTURES IN 2D, 3D AND 4D, 2019, 580
[2]   SELECTING HIGH-TEMPERATURE STRUCTURAL INTERMETALLIC COMPOUNDS - THE ENGINEERING APPROACH [J].
ANTON, DL ;
SHAH, DM ;
DUHL, DN ;
GIAMEI, AF .
JOM-JOURNAL OF THE MINERALS METALS & MATERIALS SOCIETY, 1989, 41 (09) :12-17
[3]   EFFECT OF CARBIDE AND NITRIDE ADDITIONS ON HETEROGENEOUS NUCLEATION BEHAVIOR OF LIQUID IRON [J].
BRAMFITT, BL .
METALLURGICAL TRANSACTIONS, 1970, 1 (07) :1987-&
[4]   Liquid Phase Separation in High-Entropy AlloysA Review [J].
Derimow, Nicholas ;
Abbaschian, Reza .
ENTROPY, 2018, 20 (11)
[5]   Tuning element distribution, structure and properties by composition in high-entropy alloys [J].
Ding, Qingqing ;
Zhang, Yin ;
Chen, Xiao ;
Fu, Xiaoqian ;
Chen, Dengke ;
Chen, Sijing ;
Gu, Lin ;
Wei, Fei ;
Bei, Hongbin ;
Gao, Yanfei ;
Wen, Minru ;
Li, Jixue ;
Zhang, Ze ;
Zhu, Ting ;
Ritchie, Robert O. ;
Yu, Qian .
NATURE, 2019, 574 (7777) :223-+
[6]   Integrated design of Nb-based superalloys: Ab initio calculations, computational thermodynamics and kinetics, and experimental results [J].
Ghosh, G. ;
Olson, G. B. .
ACTA MATERIALIA, 2007, 55 (10) :3281-3303
[7]   A family of ductile intermetallic compounds [J].
Gschneidner, K ;
Russell, A ;
Pecharsky, A ;
Morris, J ;
Zhang, ZH ;
Lograsso, T ;
Hsu, D ;
Lo, CHC ;
Ye, YY ;
Slager, A ;
Kesse, D .
NATURE MATERIALS, 2003, 2 (09) :587-590
[8]   Microstructure and mechanical properties of refractory MoNbHfZrTi high-entropy alloy [J].
Guo, N. N. ;
Wang, L. ;
Luo, L. S. ;
Li, X. Z. ;
Su, Y. Q. ;
Guo, J. J. ;
Fu, H. Z. .
MATERIALS & DESIGN, 2015, 81 :87-94
[9]   Effect of Ti additions on mechanical properties of NbMoTaW and VNbMoTaW refractory high entropy alloys [J].
Han, Z. D. ;
Chen, N. ;
Zhao, S. F. ;
Fan, L. W. ;
Yang, G. N. ;
Shao, Y. ;
Yao, K. F. .
INTERMETALLICS, 2017, 84 :153-157
[10]   ELASTIC-CONSTANTS OF NIOBIUM-MOLYBDENUM ALLOYS IN TEMPERATURE-RANGE - 190 TO+100DEGREES C [J].
HUBBELL, WC ;
BROTZEN, FR .
JOURNAL OF APPLIED PHYSICS, 1972, 43 (08) :3306-&