Developing Vegetable Oil-Based High Performance Thermosetting Resins

被引：0
|
作者：
Xin, Junna [1 ]
Zhang, Pei [2 ]
Huang, Kun [3 ]
Zhang, Jinwen [1 ]
机构：
[1] Washington State Univ, Composite Mat & Engn Ctr, Pullman, WA 99164 USA
[2] Jiangsu HaiCi Biol Pharmaceut Co Ltd, Yangtze River Pharmaceut Grp, Tai Zhou, Jiangsu, Peoples R China
[3] Inst Chem Ind Forestry Prod, Nanjing, Jiangsu, Peoples R China
来源：
SOY-BASED CHEMICALS AND MATERIALS | 2014年 / 1178卷
关键词：
PHASE-TRANSFER CATALYSIS; EPOXIDIZED LINSEED OIL; EPOXY-RESINS; BIOBASED EPOXY; SOYBEAN OIL; ENGINEERING PLASTICS; RENEWABLE RESOURCES; CURED EPOXY; LIGNIN; ACID;
D O I：
暂无
中图分类号：
Q81 [生物工程学（生物技术）]; Q93 [微生物学];
学科分类号：
071005 ; 0836 ; 090102 ; 100705 ;
摘要：
Renewable thermosetting resins were developed from the vegetable oil feedstocks. Acrylated soybean oil (ASO) was prepared using a novel one-step acrylation of soybean oil (SO) and copolymerization of the ASO and styrene was demonstrated. The flexural and dynamic mechanical properties of the resulting crosslinked copolymer were evaluated. Biobased epoxy monomers, including rosin-derived diglycidyl ether, fatyy acid-derived diglycidyl ether and triglycidyl ether, were synthesized. A series of epoxy resins with various properties could be obtained by adjusting the composition of the resin compositions. Flexural, impact and dynamic mechanical properties of the cured resins were also determined. Especially, the epoxy resins derived from triglycidyl ester displayed comparable strength, modulus and glass transition temperature to that of DER332. Combining the rigid rosin-derived epoxy and the flexible dimer acid one could result in resins with balanced properties and overall improved performance.
引用
收藏
页码：299 / +
页数：5
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