One trinuclear iron(III) cluster containing a triangular Fe3(μ3-O) core: crystal structure, fluorescence and Hirshfeld surface analysis

被引：0
|
作者：
Feng, Chao [1 ]
Guo, Jing-Jing [1 ,2 ]
Wang, Kai-Lun [1 ]
机构：
[1] Bengbu Univ, Sch Mat & Chem Engn, Bengbu, Peoples R China
[2] Bengbu Univ, Sch Mech & Vehicle Engn, Bengbu, Peoples R China
来源：
INORGANIC AND NANO-METAL CHEMISTRY | 2022年
关键词：
Fe(III) cluster; crystal structure; fluorescence; Hirshfeld surface; COORDINATION POLYMERS; PI-INTERACTIONS; COMPLEXES; PHOTOLUMINESCENT; ZN(II); CU(II); ACID;
D O I：
10.1080/24701556.2022.2072343
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A triazole carboxylic complex, namely, [Fe-3(mu(3)-O)(pmta)(6)(H2O)(3)]center dot Cl (1), (Hpmta: 5-methyl-1-phenyl-1H-1,2,3-triazole-4-carboxylic acid) has been synthesized under solvothermal conditions, and the crystal structure was determined by single crystal X-ray diffraction. The X-ray study reveals that complex 1 is a trinuclear cluster containing a triangular Fe-3(mu(3)-O) core. The fluorescent property of the title complex was examined in liquid state and compared with the free ligand. In order to investigate the intermolecular interactions, we also studied the Hirshfeld surface analysis of 1. The Hirshfeld surface shows that the main intermolecular interactions are H center dot center dot center dot H and N center dot center dot center dot H/H center dot center dot center dot N interactions.
引用
收藏
页码：393 / 397
页数：5
相关论文
共 50 条
  • [31] Synthesis, crystal structure, Hirshfeld surface analysis and DFT calculations of the coordination compound tetraaquabis{2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetato-κO}cobalt(II)
    Kinshakova, Ekaterina
    Torambetov, Batirbay
    Kaur, Simranjeet
    Ashurov, Jamshid
    Kadirova, Shakhnoza
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2025, 81 : 63 - +
  • [32] Crystal structure, Hirshfeld surface analysis and DFT studies of (E)-1-(4-bromopnenyl)-3-(3-fluorophenyl)prop-2-en-1-one
    Zaini, Muhamad Fikri
    Razak, Ibrahim Abdul
    Anis, Mohamad Zahid
    Arshad, Suhana
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2019, 75 : 58 - +
  • [33] Crystal structure and Hirshfeld surface analysis of (1H-imidazole-κN3)[N-(2-oxidobenzylidene)-tyrosinato-κ3O,N,O′]copper(II)
    Suzuki, Soma
    Akiyama, Yukihito
    Nakane, Daisuke
    Akitsu, Takashiro
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2023, 79 : 596 - +
  • [34] Crystal structure and Hirshfeld surface analysis of (aqua-κO)(methanol-κO)[N-(2-oxidobenzylidene)-threoninato-κ3O,N,O′]copper(II)
    Katsuumi, Natsuki
    Onami, Yuika
    Pradhan, Sayantan
    Haraguchi, Tomoyuki
    Akitsu, Takashiro
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2020, 76 : 1539 - +
  • [35] 12-(3,4,5-Trimethoxyphenyl)-2,3,4,12-tetrahydro-1H-5-oxatetraphen-1-one: crystal structure and Hirshfeld surface analysis
    Jotani, Mukesh M.
    Iniyavan, P.
    Vijayakumar, V.
    Sarveswari, S.
    Tan, Yee Seng
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 809 - +
  • [36] Crystal structure and Hirshfeld surface analysis of (Z)-3-methyl-4-(thiophen-2-ylmethylidene)isoxazol-5(4H)-one
    Laroum, Rima
    Benouatas, Assia
    Hamdouni, Noudjoud
    Zemamouche, Wissame
    Boudjada, Ali
    Debache, Abdelmadjid
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2021, 77 : 378 - +
  • [37] Synthesis, crystal structure, DFT calculations and Hirshfeld surface analysis of 3-butyl-2,6-bis(4-fluorophenyl)piperidin-4-one
    Anitha, K.
    Sivakumar, S.
    Arulraj, R.
    Rajkumar, K.
    Kaur, Manpreet
    Jasinski, Jerry P.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2020, 76 : 651 - +
  • [38] Crystal structure and Hirshfeld surface analysis of (2E)-3-(3-bromo-4-fluorophenyl)-1-(3,4-dimethoxyphenyl)prop-2-en-1-one
    Sheshadri, S. N.
    Atioglu, Zeliha
    Akkurt, Mehmet
    Veeraiah, M. K.
    Quah, Ching Kheng
    Kumar, C. S. Chidan
    Siddaraju, B. P.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 1063 - +
  • [39] Crystal structure and Hirshfeld surface analysis of 4-(2-chloroethyl)-5-methyl-1,2-dihydropyrazol-3-one
    Naghiyev, Farid N.
    Khrustalev, Victor N.
    Akkurt, Mehmet
    Dukhnovsky, Evgeny A.
    Bhattarai, Ajaya
    Khalilov, Ali N.
    Mamedov, Ibrahim G.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2024, 80 : 223 - +
  • [40] Crystal structure and Hirshfeld surface analysis of 4-(4-methylbenzyl)-6-phenylpyridazin-3(2H)-one
    Daoui, Said
    Cinar, Emine Berrin
    El Kalai, Fouad
    Saddik, Rafik
    Karrouchi, Khalid
    Benchat, Noureddine
    Baydere, Cemile
    Dege, Necmi
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2019, 75 : 1352 - +
12345