One trinuclear iron(III) cluster containing a triangular Fe3(μ3-O) core: crystal structure, fluorescence and Hirshfeld surface analysis

被引：0
|
作者：
Feng, Chao [1 ]
Guo, Jing-Jing [1 ,2 ]
Wang, Kai-Lun [1 ]
机构：
[1] Bengbu Univ, Sch Mat & Chem Engn, Bengbu, Peoples R China
[2] Bengbu Univ, Sch Mech & Vehicle Engn, Bengbu, Peoples R China
来源：
INORGANIC AND NANO-METAL CHEMISTRY | 2022年
关键词：
Fe(III) cluster; crystal structure; fluorescence; Hirshfeld surface; COORDINATION POLYMERS; PI-INTERACTIONS; COMPLEXES; PHOTOLUMINESCENT; ZN(II); CU(II); ACID;
D O I：
10.1080/24701556.2022.2072343
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A triazole carboxylic complex, namely, [Fe-3(mu(3)-O)(pmta)(6)(H2O)(3)]center dot Cl (1), (Hpmta: 5-methyl-1-phenyl-1H-1,2,3-triazole-4-carboxylic acid) has been synthesized under solvothermal conditions, and the crystal structure was determined by single crystal X-ray diffraction. The X-ray study reveals that complex 1 is a trinuclear cluster containing a triangular Fe-3(mu(3)-O) core. The fluorescent property of the title complex was examined in liquid state and compared with the free ligand. In order to investigate the intermolecular interactions, we also studied the Hirshfeld surface analysis of 1. The Hirshfeld surface shows that the main intermolecular interactions are H center dot center dot center dot H and N center dot center dot center dot H/H center dot center dot center dot N interactions.
引用
收藏
页码：393 / 397
页数：5
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