Two New Alkaline Metal Borates with Supramolecular Framework Constructed from 1D {B5}/{B6} Helical Chains

被引：4
|
作者：
Qiu Qiming [1 ]
Sun Kening [1 ]
Yang Guoyu [1 ]
机构：
[1] Beijing Inst Technol, Sch Chem & Chem Engn, Minist Educ, Key Lab Cluster Sci, Beijing 100081, Peoples R China
来源：
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES | 2020年 / 36卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Alkaline metal borate; Solvothermal synthesis; Helical chain; Supramolecular framework; NONLINEAR-OPTICAL CRYSTAL; BOND-VALENCE PARAMETERS; INORGANIC CATIONS; CO;
D O I：
10.1007/s40242-020-9097-2
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two new alkaline metal borates containing 1D {B-5}/{B-6} oxoboron helical chains, namely Na-0.5[B5O8(OH)(2)](0.5)[B5O6(OH)(2)](0.5)center dot 0.5H(3)O(1) and NaKCs[B6O9(OH)(3)](2) were synthesized under solvothermal conditions. Compound 1 contains the interesting alternative left- and right-handed helical {[B5O8(OH)(2)][B5O6(OH)(2)]}(2-) ({B-5}-1 and {B-5}-2) 1D chains and compound 2 possesses the similar [B6O11(OH)(3)](7-)({B-6}) chains. Their 1D chains are further assembled into 2D layers and 3D supramolecular frameworks through O-HMIDLINE HORIZONTAL ELLIPSISO hydrogen bonds. In addition, the UV cutoff edge of compounds 1 and 2 is both below 190 nm.
引用
收藏
页码：86 / 90
页数：5
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