Polyhydroxyalkanoates based copolymers

被引：35

作者：

Samui, Asit Baran ^{[1
]}

Kanai, Tapan ^{[2
]}

机构：

[1] Inst Chem Technol, Nathalal Parekh Marg, Mumbai 400019, Maharashtra, India

[2] Naval Mat Res Lab, Thana, Maharashtra, India

来源：

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES | 2019年 / 140卷

关键词：

Polyhudroxy alkanoate copolymers; Grafting; Click chemistry; Bacterial method of synthesis; Characterization; BIODEGRADABLE AMPHIPHILIC POLY(ETHYLENE; INDUCED GRAFT-POLYMERIZATION; POLY EPSILON-CAPROLACTONE; MICROBIAL-DEGRADATION; MECHANICAL-PROPERTIES; RALSTONIA-EUTROPHA; BLOCK-COPOLYMERS; MULTIBLOCK COPOLYMERS; ENZYMATIC DEGRADATION; THERMAL-DEGRADATION;

D O I：

10.1016/j.ijbiomac.2019.08.147

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Polyhydroxyalkanoates (PHAs) belong to a family of natural polyesters and are produced under unbalanced growth conditions as intracellular carbon and energy reserves by a wide variety of microorganisms. Being biodegradable, biocompatible and environmental friendly thermoplastics, the PHAs are considered as future polymers to replace petrochemicals based plastics. In this review, the introduction section deals with the brief discussion on PHA nature, availability, raw materials for production, processing etc. This is followed by the discussions on modifications. The copolymer syntheses by bacterial and chemical methods have been discussed. Under chemical methods, unsaturated side chains and their derivatives, oligomer, coupling, macro-initiating, trans-esterification, radiation grafting, click chemistry, ring opening and several miscellaneous polymerization methods have been elaborated. A brief discussion on applications has been incorporated. The last section includes conclusion and future perspectives. (C) 2019 Elsevier B.V. All rights reserved.

引用

页码：522 / 537

页数：16

共 138 条

[81] Form and function of the bacterial cytokinetic ring [J].

Meier, Elizabeth L. ;

Goley, Erin D. .

CURRENT OPINION IN CELL BIOLOGY, 2014, 26 :19-27

[82] Engineering the diversity of polyesters [J].

Meng, De-Chuan ;

Shen, Rui ;

Yao, Hui ;

Chen, Jin-Chun ;

Wu, Qiong ;

Chen, Guo-Qiang .

CURRENT OPINION IN BIOTECHNOLOGY, 2014, 29 :24-33

[83] Oxidative degradation of poly(3-hydroxybutyrate). A new method of synthesis for the malic acid copolymers [J].

Michalak, Michal ;

Kwiecien, Michal ;

Kawalec, Michal ;

Kurcok, Piotr .

RSC ADVANCES, 2016, 6 (16) :12809-12818

[84] RADIATION-INDUCED GRAFT-POLYMERIZATION OF POLY(3-HYDROXYBUTYRATE) AND ITS COPOLYMER [J].

MITOMO, H ;

ENJOJI, T ;

WATANABE, Y ;

YOSHII, F ;

MAKUUCHI, K ;

SAITO, T .

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 1995, A32 (03) :429-442

[85] CRYSTALLIZATION AND MORPHOLOGY OF POLY(BETA-HYDROXYBUTYRATE) AND ITS COPOLYMER [J].

MITOMO, H ;

BARHAM, PJ ;

KELLER, A .

POLYMER JOURNAL, 1987, 19 (11) :1241-1253

[86] Lamellar thickening and cocrystallization of poly(hydroxyalkanoate)s on annealing [J].

Mitomo, H ;

Doi, Y .

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 1999, 25 (1-3) :201-205

[87] Anaerobic biodegradation of the microbial copolymer poly(3-hydroxybutyrate-co-3-hydroxyhexanoate): Effects of comonomer content, processing history, and semi-crystalline morphology [J].

Morse, Margaret-Catherine ;

Liao, Qi ;

Criddle, Craig S. ;

Frank, Curtis W. .

POLYMER, 2011, 52 (02) :547-556

[88] Atom transfer radical copolymerization of bacterial poly(3-hydroxybutyrate) macromonomers and methyl methacrylate [J].

Nguyen, S ;

Marchessault, RH .

MACROMOLECULES, 2005, 38 (02) :290-296

[89] Thermal degradation of poly(3-hydroxyalkanoates): Preparation of well-defined oligomers [J].

Nguyen, S ;

Yu, GE ;

Marchessault, RH .

BIOMACROMOLECULES, 2002, 3 (01) :219-224

[90]

Nishida Haruo, 1993, Journal of Environmental Polymer Degradation, V1, P65, DOI 10.1007/BF01457654

← 4 5 6 7 8 9 10 11 12 13 →