Caged phosphorane with P-C bond based on chloral and 4,5-dimethyl-2-(2-oxo-1,2-diphenylethoxy)-1,3,2-dioxaphospholane

被引：8

作者：

Mironov, V. F. ^{[1
,2
]}

Dimukhametov, M. N. ^{[1
]}

Mironova, E. V. ^{[1
,2
]}

Krivolapov, D. B. ^{[1
]}

Ivkova, G. A. ^{[2
]}

Abdrakhmanova, L. M. ^{[1
]}

机构：

[1] Russian Acad Sci, AE Arbuzov Organ & Phys Chem Inst, Kazan Res Ctr, Kazan 420088, Tatarstan, Russia

[2] Kazan Fed Univ, Kazan, Tatarstan, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2015年 / 85卷 / 02期

基金：

俄罗斯基础研究基金会;

关键词：

dioxaphospholane; caged phosphorane; chloral; cascade reaction; 1-hydroxyphosphonate; PHOSPHONOUS ACID DICHLORIDES; TRICYCLIC PHOSPHORANES; 5-COORDINATE PHOSPHORUS; BICYCLIC PHOSPHORANES; CRYSTAL-STRUCTURE; CARBONYL; DIALKYLALKYNYLPHOSPHONITES; TRIQUINPHOSPHORANES; HEXAFLUOROACETONE; DERIVATIVES;

D O I：

10.1134/S1070363215020164

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The key methods of caged phosphoranes synthesis are analyzed. Reaction of 4,5-dimethyl-2-(2-oxo-1,2-diphenylethoxy)-1,3,2-dioxaphospholane (prepared from the meso-form of 2,3-butanediol) with chloral has yielded the caged phosphorane containing a phosphorus-carbon bond: 1,1-(1,2-dimethylethylenedioxy)-3,4-diphenyl-6-trichloromethyl-2,5,7,1-trioxaphosphabicyclo[2.2.1(1,4)]heptane; spatial structure of the product has been elucidated with X-ray diffraction analysis.

引用

页码：450 / 461

页数：12

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