Extended π-conjugated ruthenium zinc-porphyrin complexes with enhanced nonlinear-optical properties

被引：50

作者：

de Torres, Miriam ^{[1
]}

Semin, Sergey ^{[1
]}

Razdolski, Ilya ^{[1
]}

Xu, Jialiang ^{[1
]}

Elemans, Johannes A. A. W. ^{[1
]}

Rasing, Theo ^{[1
]}

Rowan, Alan E. ^{[1
]}

Nolte, Roeland J. M. ^{[1
]}

机构：

[1] Radboud Univ Nijmegen, Inst Mol & Mat, NL-6525 AJ Nijmegen, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 14期

基金：

欧洲研究理事会;

关键词：

MOLECULAR MATERIALS; COORDINATION; LIGANDS; SYSTEMS;

D O I：

10.1039/c4cc09592h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zinc porphyrin dimers and trimers, in which the porphyrins are connected via a ruthenium metal core, exhibit large third-order nonlinear optical absorption coefficients and refractive indices. These properties are a result of the presence of multiple porphyrins, which lead to an extension of the pi-conjugated system and the octupolar effect.

引用

页码：2855 / 2858

页数：4

共 35 条

[21] Molecular engineering of octupolar NLO molecules and materials based on bipyridyl metal complexes [J].

Maury, O ;

Le Bozec, H .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (09) :691-704

[22] Synthesis, characterization and sensitization properties of two novel mono and bis carboxyl-dipyrido-phenazine ruthenium(II) charge transfer complexes [J].

Mitsopoulou, Christiana A. ;

Veroni, Irene ;

Philippopoulos, Athanassios I. ;

Falaras, Polycarpos .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2007, 191 (01) :6-12

[23] Phenanthroline-appended porphyrazines: synthesis and conversion into solitaire Ru(II) complexes [J].

Montalban, AG ;

Sakellariou, EG ;

Riguet, E ;

McCubbin, QJ ;

Barrett, AGM ;

Hoffman, BM .

INORGANICA CHIMICA ACTA, 2001, 317 (1-2) :143-148

[24] Sevenfold enhancement on porphyrin dye efficiency by coordination of ruthenium polypyridine complexes [J].

Parussulo, Andre L. A. ;

Iglesias, Bernardo A. ;

Toma, Henrique E. ;

Araki, Koiti .

CHEMICAL COMMUNICATIONS, 2012, 48 (55) :6939-6941

[25] Two-Photon Absorption and the Design of Two-Photon Dyes [J].

Pawlicki, Milosz ;

Collins, Hazel A. ;

Denning, Robert G. ;

Anderson, Harry L. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (18) :3244-3266

[26] Efficient Routes to A3B-Type meso-(4-Carboxyphenyl) Porphyrin Derivatives [J].

Presolski, Stanislav I. ;

van der Weegen, Rob ;

Wiesfeld, Jan J. ;

Meijer, E. W. .

ORGANIC LETTERS, 2014, 16 (07) :1864-1867

[27] Nonlinear optical properties of porphyrins [J].

Senge, Mathias O. ;

Fazekas, Marijana ;

Notaras, Eleni G. A. ;

Blau, Werner J. ;

Zawadzka, Monika ;

Locos, Oliver B. ;

Mhuircheartaigh, Eimhin M. Ni .

ADVANCED MATERIALS, 2007, 19 (19) :2737-2774

[28] SENSITIVE MEASUREMENT OF OPTICAL NONLINEARITIES USING A SINGLE BEAM [J].

SHEIKBAHAE, M ;

SAID, AA ;

WEI, TH ;

HAGAN, DJ ;

VANSTRYLAND, EW .

IEEE JOURNAL OF QUANTUM ELECTRONICS, 1990, 26 (04) :760-769

[29] Supramolecular assemblies of ruthenium complexes and porphyrins [J].

Toma, HE ;

Araki, K .

COORDINATION CHEMISTRY REVIEWS, 2000, 196 :307-329

[30]

Toma HE, 2003, J BRAZIL CHEM SOC, V14, P845

← 1 2 3 4 →