Extended π-conjugated ruthenium zinc-porphyrin complexes with enhanced nonlinear-optical properties

被引：50

作者：

de Torres, Miriam ^{[1
]}

Semin, Sergey ^{[1
]}

Razdolski, Ilya ^{[1
]}

Xu, Jialiang ^{[1
]}

Elemans, Johannes A. A. W. ^{[1
]}

Rasing, Theo ^{[1
]}

Rowan, Alan E. ^{[1
]}

Nolte, Roeland J. M. ^{[1
]}

机构：

[1] Radboud Univ Nijmegen, Inst Mol & Mat, NL-6525 AJ Nijmegen, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 14期

基金：

欧洲研究理事会;

关键词：

MOLECULAR MATERIALS; COORDINATION; LIGANDS; SYSTEMS;

D O I：

10.1039/c4cc09592h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zinc porphyrin dimers and trimers, in which the porphyrins are connected via a ruthenium metal core, exhibit large third-order nonlinear optical absorption coefficients and refractive indices. These properties are a result of the presence of multiple porphyrins, which lead to an extension of the pi-conjugated system and the octupolar effect.

引用

页码：2855 / 2858

页数：4

共 35 条

[1] The synthesis of tetrahedral bipyridyl metallo-octupoles with large second- and third-order nonlinear optical properties [J].

Akdas-Kilig, Huriye ;

Malval, Jean-Pierre ;

Morlet-Savary, Fabrice ;

Singh, Anu ;

Toupet, Loic ;

Ledoux-Rak, Isabelle ;

Zyss, Joseph ;

Le Bozec, Hubert .

DYES AND PIGMENTS, 2012, 92 (01) :681-688

[2] Photochemistry of trans- and cis-[RuCl2(dmso)4] in aqueous and nonaqueous solutions [J].

Brindell, Malgorzata ;

Stochel, Grazyna ;

Bertolasi, Valerio ;

Boaretto, Rita ;

Sostero, Silvana .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, (16) :2353-2359

[3] Synthesis of nickel(II) complexes containing modified phenanthroline ligands for potential nonlinear optical applications [J].

Cai, Zhi-Bin ;

Liu, Li-Fen ;

Zhou, Mao .

OPTICAL MATERIALS, 2013, 35 (07) :1481-1486

[4] Developing iron and ruthenium complexes for potential nonlinear optical applications [J].

Coe, Benjamin J. .

COORDINATION CHEMISTRY REVIEWS, 2013, 257 (9-10) :1438-1458

[5] Role of structural factors in the nonlinear optical properties of phthalocyanines and related compounds [J].

de la Torre, G ;

Váquez, P ;

Agulló-López, F ;

Torres, T .

CHEMICAL REVIEWS, 2004, 104 (09) :3723-3750

[6] Cubic nonlinear optical properties of new zinc tetraphenyl porphyrins peripherally functionalized with electron-rich Ru(II) alkynyl substituents [J].

Drouet, Samuel ;

Merhi, Areej ;

Yao, Dandan ;

Cifuentes, Marie P. ;

Humphrey, Mark G. ;

Wielgus, Malgorzata ;

Olesiak-Banska, Joanna ;

Matczyszyn, Katarzyna ;

Samoc, Marek ;

Paul, Frederic ;

Paul-Roth, Christine O. .

TETRAHEDRON, 2012, 68 (50) :10351-10359

[7] Nonlinear refraction in CS2 [J].

Ganeev, RA ;

Ryasnyansky, AI ;

Baba, M ;

Suzuki, M ;

Ishizawa, N ;

Turu, M ;

Sakakibara, S ;

Kuroda, H .

APPLIED PHYSICS B-LASERS AND OPTICS, 2004, 78 (3-4) :433-438

[8] Toward Organic All-Optical Switching [J].

Haque, Saif A. ;

Nelson, Jenny .

SCIENCE, 2010, 327 (5972) :1466-1467

[9] Multiphoton absorbing materials: Molecular designs, characterizations, and applications [J].

He, Guang S. ;

Tan, Loon-Seng ;

Zheng, Qingdong ;

Prasad, Paras N. .

CHEMICAL REVIEWS, 2008, 108 (04) :1245-1330

[10] Ordered Nanosphere Alignment of Porphyrin for the Improvement of Nonlinear Optical Properties [J].

Huang, Changshui ;

Li, Yuliang ;

Song, Yinglin ;

Li, Yongjun ;

Liu, Huibiao ;

Zhu, Daoben .

ADVANCED MATERIALS, 2010, 22 (32) :3532-+

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