Catalytic oxidation of volatile organic compounds on supported noble metals

被引:775
作者
Liotta, L. F. [1 ]
机构
[1] CNR, ISMN, I-90146 Palermo, Italy
关键词
Volatile organic compounds; Catalytic oxidation; Pt Pd Rh catalysts; Particle size effect; Chlorine poisoning; gamma Al2O3; Transition metal oxides; DEEP OXIDATION; PT/AL2O3; CATALYSTS; N-HEXANE; ROOM-TEMPERATURE; COMPOUNDS VOCS; PLATINUM; COMBUSTION; TOLUENE; HYDROCARBONS; ALUMINA;
D O I
10.1016/j.apcatb.2010.08.023
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Volatile organic compounds (VOCs) are toxic and mainly contribute to the formation of photochemical smog with a consequent remarkable impact to the air quality A few techniques are available to reduce VOC emission among them catalytic oxidation is suitable especially for highly diluted VOCs The development of noble metals and transition metal oxides as catalysts for VOCs oxidation has been widely reported in the literature and the research field continues to be very active Selection of catalytic materials for the abatement of organic pollutants is not easy because the activity depends on the specific molecule on the reactions conditions and many parameters can affect the catalyst activity and resistance The present review focus on the most used noble metals catalysts for oxidation of not halogenated VOC The effects of metal salt precursor chlorine poisoning water inhibition particle size dependence nature of the support are discussed The calculated reaction order with respect to VOC and oxygen as well as the proposed reaction mechanisms are addressed Examples of the most recent catalytic systems reported in literature are also Included (C) 2010 Elsevier B V All rights reserved
引用
收藏
页码:403 / 412
页数:10
相关论文
共 67 条
[1]   The revision of the air quality legislation in the European Union related to ground-level ozone [J].
Amann, M ;
Lutz, M .
JOURNAL OF HAZARDOUS MATERIALS, 2000, 78 (1-3) :41-62
[2]  
[Anonymous], CITEPA REPORT
[3]  
[Anonymous], 1999, P 8 INT S TRANSP AIR
[4]  
[Anonymous], 2002, CATALYTIC POLLUTION
[5]   The effect of platinum distribution in monolithic catalysts on the oxidation of CO and hydrocarbons [J].
Arnby, K ;
Assiks, J ;
Carlsson, PA ;
Palmqvist, A ;
Skoglundh, M .
JOURNAL OF CATALYSIS, 2005, 233 (01) :176-185
[6]  
Arts J., 1992, POLLUT ATMOS, V134, P18
[7]   MODEL FOR CATALYTIC-OXIDATION OF HYDROCARBONS IN VAPOR-PHASE [J].
BALASUBRAMANIAN, S ;
VISWANATH, DS .
INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1975, 14 (03) :158-165
[8]   Supported platinum catalysts for nitrogen oxide sensors [J].
Benard, S ;
Retailleau, L ;
Gaillard, F ;
Vernoux, P ;
Giroir-Fendler, A .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2005, 55 (01) :11-21
[9]   Catalytic removal of propene and toluene in air over noble metal catalyst [J].
Benard, S. ;
Ousmane, M. ;
Retailleau, L. ;
Boreave, A. ;
Vernoux, P. ;
Giroir-Fendler, A. .
CANADIAN JOURNAL OF CIVIL ENGINEERING, 2009, 36 (12) :1935-1945
[10]  
BENARD S, 2010, CATAL TODAY, DOI DOI 10.1016/JCATTOD201007019