Implementation and physico-chemical characterization of new alkali-modified bio-sorbents for cadmium removal from industrial discharges: Adsorption isotherms and kinetic approaches

被引：20
作者：
Kasbaji, Meriem [1 ,2 ]
Mennani, Mehdi [2 ]
Grimi, Nabil [3 ]
Barba, Francisco J. [4 ]
Oubenali, Mustapha [1 ]
Simirgiotis, Mario J. [5 ]
Mbarki, Mohammed [1 ]
Moubarik, Amine [2 ]
机构：
[1] Sultan Moulay Slimane Univ, Fac Sci & Technol, Lab Engn Chem & Phys Matter, PB 52, Beni Mellal, Morocco
[2] Sultan Moulay Slimane Univ, Polydisciplinary Fac, Lab Chem Proc & Appl Mat, BP 592, Beni Mellal, Morocco
[3] Sorbonne Univ, Univ Technol Compiegne, Royally Res Ctr, Integrated Transformat Renewable Matter Lab,UTC ES, 60 319, F-60203 Compiegne, France
[4] Univ Valencia, Fac Pharm, Prevent Med & Publ Hlth,Food Sci Toxicol & Forens, Nutr & Food Sci Area, Avda Vicent Andres Estelles, s-n, Burjassot 46100, Valencia, Spain
[5] Univ Austral Chile, Inst Pharm, Fac Sci, Campus Isla Teja, Valdivia 5090000, Chile
来源：
PROCESS BIOCHEMISTRY | 2022年 / 120卷
关键词：
Bio-adsorption; Lignocellulosic waste; Mercerization; Cadmium; Isotherms; AQUEOUS-SOLUTIONS; CD(II); WASTE; NANOCRYSTALS; EQUILIBRIUM; BIOSORPTION; BAGASSE; FIBERS; CR(VI); IONS;
D O I：
10.1016/j.procbio.2022.06.010
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
This study consists of using for the first-time new alkali-modified natural adsorbents as underused lignocellulosic remains in a physicochemical adsorption process, to treat polluted discharges of industrial origin. Four different lignocellulosic materials were mercerized using sodium hydroxide (NaOH) and tested to investigate their ability to adsorb cadmium II (Cd2+) as a toxic heavy metal ion. The physicochemical features and the performance of the bio-sorbents were evaluated by FTIR, BET, SEM, TGA, XRD and zeta potential analysis. The influence of different experimental parameters (solution pH, temperature, contact time, and Cd2+ concentration) was studied. Results showed that the treated bio-sorbents exhibited remarkable elimination from the first 25 min. Among the used lignocellulosic materials red algae (RA) exhibited the highest adsorption percentages (99.54%) at neutral pH (7) and room temperature (25 degrees C). Interestingly, the kinetic adsorption model (pseudo-secondary order) adequately simulates the Cd2+ adsorption behavior. Also, Langmuir model exhibited a correlation coefficient (R2) close to 1. These results demonstrated high adsorption capacities of all the lignocellulosic materials used. Accordingly, their physico-chemical characterization and application can open new perspectives for the development of high valueadded materials from under-exploited lignocellulosic products.
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收藏
页码：213 / 226
页数：14
相关论文
共 44 条
[1]   Evaluation of mercerization treatment conditions on extracted cellulose from shea nut shell using FTIR and thermogravimetric analysis [J].
Agwuncha, Stephen Chinenyeze ;
Owonubi, Shesan ;
Fapojuwo, Dele Peter ;
Abdulkarim, Awwal ;
Okonkwo, Tochukwu Perpetua ;
Makhatha, Elizabeth Mamookho .
MATERIALS TODAY-PROCEEDINGS, 2021, 38 :958-963
[2]   Effect of alkali treatment and coupling agent on thermal and mechanical properties of Opuntia ficus-indica cladodes fibers reinforced HDPE composites [J].
Ait Benhamou, Anass ;
Boussetta, Abdelghani ;
Nadifiyine, Mehdi ;
Moubarik, Amine .
POLYMER BULLETIN, 2022, 79 (04) :2089-2111
[3]   Multiuse silicon hybrid polyurea-based polymer for highly effective removal of heavy metal ions from aqueous solution [J].
Aldawsari, A. M. ;
Alsohaimi, I. H. ;
Hassan, H. M. A. ;
Al-Abduly, A. J. ;
Hassan, I ;
Saleh, E. A. M. .
INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY, 2022, 19 (04) :2925-2938
[4]   Tailoring an efficient nanocomposite of activated carbon-layered double hydroxide for elimination of water-soluble dyes [J].
Aldawsari, Abdullah M. ;
Alsohaimi, Ibrahim ;
Hassan, Hassan M. A. ;
Abdalla, Zaki E. A. ;
Hassan, Ismail ;
Berber, Mohamed R. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2021, 857
[5]   Activated carbon/MOFs composite: AC/NH2-MIL-101(Cr), synthesis and application in high performance adsorption of p-nitrophenol [J].
Aldawsari, Abdullah M. ;
Alsohaimi, Ibrahim Hotan ;
Hassan, Hassan M. A. ;
Berber, Mohamed R. ;
Abdalla, Zaki E. A. ;
Hassan, Ismail ;
Saleh, Ebraheem Abdu Musad ;
Hameed, Bassim H. .
JOURNAL OF SAUDI CHEMICAL SOCIETY, 2020, 24 (09) :693-703
[6]   Adsorptive performance of aminoterephthalic acid modified oxidized activated carbon for malachite green dye: mechanism, kinetic and thermodynamic studies [J].
Aldawsari, Abdullah Mohammed ;
Alsohaimi, Ibrahim Hotan ;
Al-Kahtani, Abdullah A. ;
Alqadami, Ayoub Abdullah ;
Abdalla, Zaki Eldin ;
Saleh, Ebraheem Abdu Musad .
SEPARATION SCIENCE AND TECHNOLOGY, 2021, 56 (05) :835-846
[7]   Selective and efficient sequestration of Cr(VI) in ground water using trimethyloctadecylammonium bromide impregnated on Artemisia monosperma plant powder [J].
Ali, Hazim M. ;
Essawy, Amr A. ;
Elnasr, Tarek A. Seaf ;
Aldawsari, Abdullah M. ;
Alsohaimi, Ibrahim ;
Hassan, Hassan M. A. ;
Abdel-Farid, Ibrahim Bayoumi .
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2021, 125 :122-131
[8]   Removal of nickel (II) ions from aqueous solutions by biosorption on sugarcane bagasse [J].
Aloma, I. ;
Martin-Lara, M. A. ;
Rodriguez, I. L. ;
Blazquez, G. ;
Calero, M. .
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2012, 43 (02) :275-281
[9]   Adsorptive performance of tetracarboxylic acid-modified magnetic silica nanocomposite for recoverable efficient removal of toxic Cd(II) from aqueous environment: Equilibrium, isotherm, and reusability studies [J].
Alosaimi, Eid H. ;
Alsohaimi, Ibrahim Hotan ;
Dahan, Talal E. ;
Chen, Qiao ;
Melhi, Saad .
JOURNAL OF MOLECULAR LIQUIDS, 2021, 334
[10]  
Belaid K., 2011, J. Water Sci, V24, P131, DOI [10.7202/1006107AR, DOI 10.7202/1006107AR]
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