Nickel-catalyzed cross-coupling of diphenylphosphine with vinyl bromides and chlorides as a route to diphenylvinylphosphines

被引：19

作者：

Shulyupin, MO ^{[1
]}

Chirkov, EA ^{[1
]}

Kazankova, MA ^{[1
]}

Beletskaya, LP ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia

来源：

SYNLETT | 2005年 / 04期

关键词：

cross-coupling; phosphorus; nickel; alkenylphosphines;

D O I：

10.1055/s-2005-863714

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient nickel-catalyzed reaction for the phosphination of vinyl bromides and chlorides was developed. The procedure uses a combination of up to 1 mol% of nickel acetylacetonate, triethylamine and dimethylformamide as a solvent. The double bond geometry of the vinyl halides was retained under the reaction conditions.

引用

页码：658 / 660

页数：3

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