Role of surface oxygen in the preparation and deactivation of carbon nanofiber supported cobalt Fischer-Tropsch catalysts

被引：21
|
作者：
Yu, Zhixin
Borg, Oyvind
Chen, De
Rytter, Erling
Holmen, Anders [1 ]
机构：
[1] Norwegian Univ Sci & Technol, Dept Chem Engn, N-7491 Trondheim, Norway
[2] Statoil R&D, N-7005 Trondheim, Norway
来源：
TOPICS IN CATALYSIS | 2007年 / 45卷 / 1-4期
关键词：
carbon nanofibers; surface oxygen groups; preparation; deactivation;
D O I：
10.1007/s11244-007-0242-7
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Surface oxygen groups on the carbon nanofiber surfaces are important for the preparation of highly dispersed cobalt catalysts and for the stabilization of the particles against sintering. However, the surface oxygen makes the catalysts easily deactivate during Fischer-Tropsch synthesis by oxidation of metallic cobalt. The activity could be recovered by re-reduction.
引用
收藏
页码：69 / 74
页数：6
相关论文
共 50 条
  • [1] Role of surface oxygen in the preparation and deactivation of carbon nanofiber supported cobalt Fischer–Tropsch catalysts
    Zhixin Yu
    Øyvind Borg
    De Chen
    Erling Rytter
    Anders Holmen
    Topics in Catalysis, 2007, 45 : 69 - 74
  • [2] Deactivation Behavior of Carbon Nanotubes Supported Cobalt Catalysts in Fischer-Tropsch Synthesis
    Trepanier, Mariane
    Tavasoli, Ahmad
    Anahid, Sanaz
    Dalai, K. Ajay
    IRANIAN JOURNAL OF CHEMISTRY & CHEMICAL ENGINEERING-INTERNATIONAL ENGLISH EDITION, 2011, 30 (01): : 37 - 47
  • [3] Role of surface carboxylate deposition on the deactivation of cobalt on titania Fischer-Tropsch catalysts
    Gonugunta, Prasad
    Dugulan, A. Iulian
    Bezemer, G. Leendert
    Bruck, Ekkes
    CATALYSIS TODAY, 2021, 369 : 144 - 149
  • [4] Carbon nanofiber supported cobalt catalysts for fischer-tropsch synthesis with high activity and selectivity
    Yu, ZX
    Borg, O
    Chen, D
    Enger, BC
    Froseth, V
    Rytter, E
    Wigum, H
    Holmen, A
    CATALYSIS LETTERS, 2006, 109 (1-2) : 43 - 47
  • [5] The Effect of Water on the Activity and Selectivity for Carbon Nanofiber Supported Cobalt Fischer-Tropsch Catalysts
    Borg, Oyvind
    Yu, Zhixin
    Chen, De
    Blekkan, Edd Anders
    Rytter, Erling
    Holmen, Anders
    TOPICS IN CATALYSIS, 2014, 57 (6-9) : 491 - 499
  • [6] Cobalt and iron supported on carbon nanofibers as catalysts for Fischer-Tropsch synthesis
    Antonio Diaz, Jose
    Akhavan, Hasti
    Romero, Amaya
    Maria Garcia-Minguillan, Alba
    Romero, Rubi
    Giroir-Fendler, A.
    Luis Valverde, Jose
    FUEL PROCESSING TECHNOLOGY, 2014, 128 : 417 - 424
  • [7] Synthesis of carbon nanofibers supported cobalt catalysts for Fischer-Tropsch process
    Diaz, Jose Antonio
    Martinez-Fernandez, Miriam
    Romero, Amaya
    Valverde, Jose Luis
    FUEL, 2013, 111 : 422 - 429
  • [8] Deactivation of Cobalt-Based Catalysts for Fischer-Tropsch Synthesis
    Shi Lihong
    Li Xiaofeng
    Li Debao
    Sun Yuhan
    CHINESE JOURNAL OF CATALYSIS, 2010, 31 (12) : 1483 - 1488
  • [9] Study on the Deactivation of Cobalt-based Fischer-Tropsch Synthesis Catalysts
    Hora, Lukas
    Rubas, Vlastimil
    Martinez, Augustin
    PROCEEDINGS OF THE 1ST INTERNATIONAL CONFERENCE ON CHEMICAL TECHNOLOGY, 2013, : 72 - 77
  • [10] Carbon Nanofiber Supported Cobalt Catalysts for Fischer–Tropsch Synthesis with High Activity and Selectivity
    Zhixin Yu
    Øyvind Borg
    De Chen
    Bjørn Christian Enger
    Vidar Frøseth
    Erling Rytter
    Hanne Wigum
    Anders Holmen
    Catalysis Letters, 2006, 109 : 43 - 47
12345