Formic acid as a hydrogen storage material - development of homogeneous catalysts for selective hydrogen release

被引：717

作者：

Mellmann, Doerthe ^{[1
]}

Sponholz, Peter ^{[1
]}

Junge, Henrik ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Albert Einstein Str 29a, D-18059 Rostock, Germany

来源：

CHEMICAL SOCIETY REVIEWS | 2016年 / 45卷 / 14期

基金：

中国博士后科学基金; 美国国家科学基金会;

关键词：

ASYMMETRIC TRANSFER HYDROGENATION; HEXACATIONIC DENDRIPHOS LIGANDS; CARBON-DIOXIDE HYDROGENATION; METAL-ORGANIC FRAMEWORKS; CROSS-COUPLING REACTION; DEFINED IRON CATALYST; FE-ONLY HYDROGENASE; IONIC LIQUIDS; RENEWABLE ENERGY; REVERSIBLE HYDROGENATION;

D O I：

10.1039/c5cs00618j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Formic acid (FA, HCO2H) receives considerable attention as a hydrogen storage material. In this respect, hydrogenation of CO2 to FA and dehydrogenation of FA are crucial reaction steps. In the past decade, for both reactions, several molecularly defined and nanostructured catalysts have been developed and intensively studied. From 2010 onwards, this review covers recent advancements in this area using homogeneous catalysts. In addition to the development of catalysts for H-2 generation, reversible H-2 storage including continuous H-2 production from formic acid is highlighted. Special focus is put on recent progress in non-noble metal catalysts.

引用

页码：3954 / 3988

页数：35

共 311 条

[1] A review on biomass-based hydrogen production and potential applications [J].