Constructing POSS and viologen-linked porous cationic frameworks induced by the Zincke reaction for efficient CO2 capture and conversion

被引：57

作者：

Chen, Guojian ^{[1
]}

Huang, Xiaohui ^{[1
]}

Zhang, Yadong ^{[1
]}

Sun, Mengyao ^{[1
]}

Shen, Jie ^{[1
]}

Huang, Rui ^{[1
]}

Tong, Minman ^{[1
]}

Long, Zhouyang ^{[1
]}

Wang, Xiaochen ^{[2
]}

机构：

[1] Jiangsu Normal Univ, Sch Chem & Mat Sci, Jiangsu Key Lab Green Synthet Chem Funct Mat, Xuzhou 221116, Jiangsu, Peoples R China

[2] Hefei Univ, Dept Chem & Mat Engn, Hefei 230022, Anhui, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 86期

基金：

中国国家自然科学基金;

关键词：

COVALENT ORGANIC FRAMEWORKS; HIGH-SURFACE-AREA; CYCLIC CARBONATES; POLY(IONIC LIQUID)S; AMBIENT CONDITIONS; CHEMICAL FIXATION; IONIC POLYMERS; HYBRID; NETWORK; POLYMERIZATION;

D O I：

10.1039/c8cc06972g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

POSS and viologen-linked porous cationic frameworks (V-PCIF-X, X = Cl, Br) are constructed via the Zincke reaction between octa(aminophenyl)silsesquioxane and viologen linkers. The typical V-PCIF-Br has a high surface area with abundant ionic sites, micro-/mesopores and Si-OH groups, serving as an efficient porous adsorbent and metal-free catalyst for simultaneous CO2 capture and conversion.

引用

页码：12174 / 12177

页数：4

共 35 条

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