A new polymorph of hexaapuamagnesium(II) bis(hypophosphite)

被引：4

作者：

Kuratieva, NV ^{[1
]}

Naumova, MI ^{[1
]}

Naumov, DY ^{[1
]}

Podberezskaya, NV ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Inorgan Chem, SB, Novosibirsk 630090 90, Russia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2003年 / 59卷

关键词：

COPPER(II); HYPOPHOSPHITE;

D O I：

10.1107/S160053680300758X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In a new polymorph of hexaaquamagnesium(II) bis( hypophosphite), [Mg(H2O)(6)](H2PO2)(2), the planes of trans water molecules forming the octahedral coordination sphere of the Mg atoms are in a staggered conformation. The magnesium(II) cations are in a pseudo-face-centered cubic arrangement, with a similar or equal to 10.294 Angstrom and tetrahedral cavities are occupied by P atoms. Hypophosphite anions are hydrogen bonded to the coordinated water molecules.

引用

页码：I89 / I91

页数：3

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