Ammonia: An Environmentally Friendly Nitrogen Source for Primary Aniline Synthesis

被引:42
作者
Enthaler, Stephan [1 ]
机构
[1] Tech Univ Berlin, Dept Chem, D-10623 Berlin, Germany
关键词
anilines; copper; homogeneous catalysis; palladium; sustainable chemistry; PALLADIUM-CATALYZED AMINATION; ARYL HALIDES; AQUEOUS AMMONIA; REDUCTIVE AMINATION; ROOM-TEMPERATURE; SELECTIVE HYDROAMINOMETHYLATION; PRIMARY ARYLAMINES; TRANSITION-METAL; GREEN CHEMISTRY; PRIMARY AMINES;
D O I
10.1002/cssc.201000145
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Got ammo? In the search for sustainable and environmentally benign primary aniline synthesis, the application of ammonia instead of currently applied ammonia surrogates is one major challenge in catalysis. Recent efforts in palladium- and copper-catalyzed transformations of ammonia to anilines are discussed in this Highlight. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:1024 / 1029
页数:6
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