Recent Advances in Copper-Catalyzed Carboxylation Reactions with CO2

被引：8

作者：

Song, Yufei ^{[1
]}

Zhang, Yu ^{[1
]}

Chen, Zhengkai ^{[1
]}

Wu, Xiao-Feng ^{[2
,3
]}

机构：

[1] Zhejiang Sci Tech Univ, Dept Chem, Key Lab Surface & Interface Sci Polymer Mat, Hangzhou 310018, Peoples R China

[2] Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

[3] Leibniz Inst Katalyse e V, Albert Einstein Str 29a, D-18059 Rostock, Germany

来源：

ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 11卷 / 07期

关键词：

CO2; utilization; carboxylation; copper catalyst; carboxylic acids; catalytic reactions; C-H BONDS; CARBON-DIOXIDE; REGIODIVERGENT SILACARBOXYLATION; GEM-DIFLUOROALKENES; EFFICIENT CATALYST; TERMINAL ALKYNES; F BOND; ARYL; ALKENES; ACIDS;

D O I：

10.1002/ajoc.202200237

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

As an ideal one-carbon synthon, CO2 has been successfully utilized in diverse carboxylation reactions to construct a series of value-added products. Among various transition-metal catalysts, the inexpensive copper complexes exhibit unique catalytic activity in carboxylation reactions. This review summarizes the recent developments in copper-catalyzed carboxylation reactions with CO2, the contents of which are divided into five parts based on the type of the substrates or products: organic halides and their surrogates, C-C double bonds, C-C triple bonds, C-H bonds and the synthesis of heterocycles.

引用

页数：12

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