ABC-type miktoarm star terpolymers accessed by H-bonding driven supramolecular self-assembly

被引：21
作者：
Altintas, Ozcan [1 ,2 ]
Schulze-Suenninghausen, David [2 ,3 ]
Luy, Burkhard [2 ,3 ]
Barner-Kowollik, Christopher [1 ,2 ]
机构：
[1] Karlsruhe Inst Technol, Inst Tech Chem & Polymerchem, D-76128 Karlsruhe, Germany
[2] Karlsruhe Inst Technol, Inst Biol Grenzflachen, D-76344 Eggenstein Leopoldshafen, Germany
[3] Karlsruhe Inst Technol, Inst Organ Chem, D-76131 Karlsruhe, Germany
来源：
EUROPEAN POLYMER JOURNAL | 2015年 / 62卷
关键词：
Supramolecular Architectures; Miktoarms Star Polymers; Hydrogenbonding; DOSY; DLS; FACILE PREPARATION; POLYMERS; COPOLYMERS;
D O I：
10.1016/j.eurpolymj.2014.04.006
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A supramolecular ABC-type miktoarm star polymer was prepared using a Hamilton wedge (HW) mid-chain functionalized polyethylene glycol-b-polystyrene (PEG-HW-PS) block copolymer and an alpha-cyanuric acid (CA) chain-end functional linear homopolymer poly(n-butylacrylate) (CA-PnBA). The PEG-HW-PS element prepared via a combination of atom transfer radical polymerization (ATRP) and copper-catalyzed azide alkyne cycloaddition (CuAAC) (M-n = 13,700 g mol(-1), PDI = 1.04). The CA-PnBA strand was synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization (M-n = 11,300 g mol(-1), PDI = 1.06). The quantitative formation of a well-defined supramolecular ABC-type miktoarm star polymer was unambiguously proven via proton nuclear magnetic resonance (H-1 NMR) spectroscopy, diffusion ordered NMR spectroscopy (DOSY) and dynamic light scattering (DLS) analyses. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码：409 / 417
页数：9
相关论文
共 41 条
[21]   Synthesis of functional polymers with controlled architecture by CRP of monomers in the presence of cross-linkers: From stars to gels [J].
Gao, Haifeng ;
Matyjaszewski, Krzysztof .
PROGRESS IN POLYMER SCIENCE, 2009, 34 (04) :317-350
[22]   Sticky Supramolecular Grafts Stretch Single Polymer Chains [J].
Gillissen, Martijn A. J. ;
Terashima, Takaya ;
Meijer, E. W. ;
Palmans, Anja R. A. ;
Voets, Ilja K. .
MACROMOLECULES, 2013, 46 (10) :4120-4125
[23]   Single chain polymeric nanoparticles as compartmentalised sensors for metal ions [J].
Gillissen, Martijn A. J. ;
Voets, Ilja K. ;
Meijer, E. W. ;
Palmans, Anja R. A. .
POLYMER CHEMISTRY, 2012, 3 (11) :3166-3174
[24]   3-miktoarm star terpolymers using triple click reactions: Diels-Alder, copper-catalyzed azide-alkyne cycloaddition, and nitroxide radical coupling reactions [J].
Gunay, Ufuk Saim ;
Durmaz, Hakan ;
Gungor, Eda ;
Dag, Aydan ;
Hizal, Gurkan ;
Tunca, Umit .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2012, 50 (04) :729-735
[25]   Counterion-Mediated Hierarchical Self-Assembly of an ABC Miktoarm Star Terpolymer [J].
Hanisch, Andreas ;
Groeschel, Andre H. ;
Foertsch, Melanie ;
Drechsler, Markus ;
Jinnai, Hiroshi ;
Ruhland, Thomas M. ;
Schacher, Felix H. ;
Mueller, Axel H. E. .
ACS NANO, 2013, 7 (05) :4030-4041
[26]   A Modular Route for the Synthesis of ABC Miktoarm Star Terpolymers via a New Alkyne-Substituted Diphenylethylene Derivative [J].
Hanisch, Andreas ;
Schmalz, Holger ;
Mueller, Axel H. E. .
MACROMOLECULES, 2012, 45 (20) :8300-8309
[27]   Study on the Formation of a Supramolecular Conjugated Graft Copolymer in Solution [J].
Hardeman, Tine ;
Willot, Pieter ;
De Winter, Julien ;
Josse, Thomas ;
Gerbaux, Pascal ;
Shestakova, Pavletta ;
Nies, Erik ;
Koeckelberghs, Guy .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2014, 52 (06) :804-809
[28]   Synthesis of well-defined star-branched polymers by stepwise iterative methodology using living anionic polymerization [J].
Higashihara, Tomoya ;
Hayashi, Mayumi ;
Hirao, Akira .
PROGRESS IN POLYMER SCIENCE, 2011, 36 (03) :323-375
[29]   Orthogonal Self-Assembly in Folding Block Copolymers [J].
Hosono, Nobuhiko ;
Gillissen, Martijn A. J. ;
Li, Yuanchao ;
Sheiko, Sergei S. ;
Palmans, Anja R. A. ;
Meijer, E. W. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (01) :501-510
[30]   Reversible side chain modification through noncovalent interactions. "Plug and play" polymers [J].
Ilhan, F ;
Gray, M ;
Rotello, VM .
MACROMOLECULES, 2001, 34 (08) :2597-2601
12345