ABC-type miktoarm star terpolymers accessed by H-bonding driven supramolecular self-assembly

被引：21

作者：

Altintas, Ozcan ^{[1
,2
]}

Schulze-Suenninghausen, David ^{[2
,3
]}

Luy, Burkhard ^{[2
,3
]}

Barner-Kowollik, Christopher ^{[1
,2
]}

机构：

[1] Karlsruhe Inst Technol, Inst Tech Chem & Polymerchem, D-76128 Karlsruhe, Germany

[2] Karlsruhe Inst Technol, Inst Biol Grenzflachen, D-76344 Eggenstein Leopoldshafen, Germany

[3] Karlsruhe Inst Technol, Inst Organ Chem, D-76131 Karlsruhe, Germany

来源：

EUROPEAN POLYMER JOURNAL | 2015年 / 62卷

关键词：

Supramolecular Architectures; Miktoarms Star Polymers; Hydrogenbonding; DOSY; DLS; FACILE PREPARATION; POLYMERS; COPOLYMERS;

D O I：

10.1016/j.eurpolymj.2014.04.006

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A supramolecular ABC-type miktoarm star polymer was prepared using a Hamilton wedge (HW) mid-chain functionalized polyethylene glycol-b-polystyrene (PEG-HW-PS) block copolymer and an alpha-cyanuric acid (CA) chain-end functional linear homopolymer poly(n-butylacrylate) (CA-PnBA). The PEG-HW-PS element prepared via a combination of atom transfer radical polymerization (ATRP) and copper-catalyzed azide alkyne cycloaddition (CuAAC) (M-n = 13,700 g mol(-1), PDI = 1.04). The CA-PnBA strand was synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization (M-n = 11,300 g mol(-1), PDI = 1.06). The quantitative formation of a well-defined supramolecular ABC-type miktoarm star polymer was unambiguously proven via proton nuclear magnetic resonance (H-1 NMR) spectroscopy, diffusion ordered NMR spectroscopy (DOSY) and dynamic light scattering (DLS) analyses. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：409 / 417

页数：9

共 23 条

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