High, internal phase emulsion foams: Copolymers, and interpenetrating polymer networks

被引:73
作者
Tai, H [1 ]
Sergienko, A [1 ]
Silverstein, MS [1 ]
机构
[1] Technion Israel Inst Technol, Dept Mat Engn, IL-32000 Haifa, Israel
关键词
D O I
10.1002/pen.10853
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
High internal phase emulsion (HIPE) copolymer and interpenetrating network foams were prepared from 2-ethylhexyl acrylate (EHA), styrene (S) and divinylbenzene (DVB) using a unique process. The morphologies, thermal properties, and dynamic and static mechanical properties of these foams were investigated. The glass transition temperatures and damping properties of the EHA/S copolymer foams vary with its composition. IPN foams with very broad tan delta peaks were obtained. The damping properties of IPN foams were tailored through changing copolymer composition and monomer composition. The IPN foams based on a copolymer foam and styrene had a broader tan delta, peak, a higher glass transition temperature and a higher modulus than the copolymer foams of similar overall styrene contents. It is therefore possible to prepare novel damping foams based on polyHIPE foams through the synthesis of interpenetrating polymer networks.
引用
收藏
页码:1540 / 1552
页数:13
相关论文
共 24 条
[1]  
Andrews RJ, 1999, Polymer Handbook, V4th
[2]  
[Anonymous], ADV CHEM SERIES
[3]  
Barby D., 1985, U.S. Patent, Patent No. [US4522953A, 4522953]
[4]   Open-celled polymeric foam monoliths for heavy metal separations study [J].
Benicewicz, BC ;
Jarvinen, GD ;
Kathios, DJ ;
Jorgensen, BS .
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 1998, 235 (1-2) :31-35
[5]  
BHUMGARA ZG, 1997, RES EV 2 DAY S, V2, P1121
[6]   ANALYSIS OF THE LINEAR METHODS FOR DETERMINING COPOLYMERIZATION REACTIVITY RATIOS .7. A CRITICAL REEXAMINATION OF RADICAL COPOLYMERIZATIONS OF STYRENE [J].
BRAUN, D ;
CZERWINSKI, W ;
DISSELHOFF, G ;
TUDOS, F ;
KELEN, T ;
TURCSANYI, B .
ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1984, 125 (OCT) :161-205
[7]  
Cameron NR, 1996, ADV POLYM SCI, V126, P163
[8]  
DESMARAIS TA, 1999, Patent No. 9947183
[9]   High temperature properties of poly(styrene-co-alkylmaleimide) foams prepared by high internal phase emulsion polymerization [J].
Duke, JR ;
Hoisington, MA ;
Langlois, DA ;
Benicewicz, BC .
POLYMER, 1998, 39 (18) :4369-4378
[10]  
DYER JC, 1996, Patent No. 9621682