C-O bond hydrogenolysis vs. C=C group hydrogenation of furfuryl alcohol: towards sustainable synthesis of 1,2-pentanediol

被引：26

作者：

Goetz, Dominik ^{[1
]}

Lucas, Martin ^{[1
]}

Claus, Peter ^{[1
]}

机构：

[1] Tech Univ Darmstadt, Dept Chem, Ernst Berl Inst Chem Technol 2, Alarich Weiss Str 8, D-64287 Darmstadt, Germany

来源：

REACTION CHEMISTRY & ENGINEERING | 2016年 / 1卷 / 02期

关键词：

TETRAHYDROFURFURYL ALCOHOL; CATALYST; CYCLOPENTANONE; REARRANGEMENT; CONVERSION; KINETICS; PHASE;

D O I：

10.1039/c5re00026b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The conversion of furfuryl alcohol into 1,2-pentanediol and tetrahydrofurfuryl alcohol by aqueous phase hydrogenolysis using highly active supported ruthenium catalysts is a promising sustainable route substituting for petro-based production processes. An on-line analysis of the reaction, performed by ATR-IR spectroscopy, is necessary to show the formation of solid deposits during the reaction.

引用

页码：161 / 164

页数：4

共 22 条

[1]

Adkins H., 1931, J. Am. Chem. Soc., V53, P1091, DOI [10.1021/ja01354a041, DOI 10.1021/JA01354A041]

[2]

Agostini I., 2001, US Pat, Patent No. 6296858

[3]

Anastas P.T., 1998, Green chemistry: theory and practice

[4] Acid-catalyzed polycondensation of furfuryl alcohol: Mechanisms of chromophore formation and cross-linking [J].