Temperature-Dependent Crystal Self-Assembly, Disassembly, and Reassembly Among Three Cadmium(II) Carboxylate-Phosphinates

被引：40

作者：

Dong, Li-Jie ^{[1
]}

Zhao, Cui-Cui ^{[1
]}

Xu, Xiang ^{[2
]}

Du, Zi-Yi ^{[1
,2
]}

Xie, Yong-Rong ^{[1
]}

Zhang, Jian ^{[2
]}

机构：

[1] Gannan Normal Univ, Coll Chem & Chem Engn, Ganzhou 341000, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2012年 / 12卷 / 04期

关键词：

COORDINATION POLYMERS; STRUCTURAL TRANSFORMATIONS; NETWORKS; COMPLEX; LIGAND; STATE;

D O I：

10.1021/cg300029d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A metastable three-dimensional cadmium(II) coordination polymer with (2-carboxyethyl)(phenyl)phosphinate (12) and 4,4'-bipyridine (bipy) as ligands, namely, [Cd(L)(bipy)(H2O)(2)] (1), can be converted to two new two-dimensional/ three-dimensional varieties under hydrothermal treatments at different temperatures, that is, [Cd(L)(bipy)] (2) and [Cd(L)(bipy)(0.5)]center dot 0.5H(2)O (3). Their syntheses, crystal structures, structural transformations, and luminescent properties are presented. In addition, 1 shows a second harmonic generation response that is similar to 0.3 tames that of KDP (KH2PO4).

引用

页码：2052 / 2058

页数：7

共 25 条

[11] Direct observation of crystalline-state guest exchange in coordination networks [J].

Kawano, Masaki ;

Fujita, Makoto .

COORDINATION CHEMISTRY REVIEWS, 2007, 251 (21-24) :2592-2605

[12] Dynamic porous properties of coordination polymers inspired by hydrogen bonds [J].

Kitagawa, S ;

Uemura, K .

CHEMICAL SOCIETY REVIEWS, 2005, 34 (02) :109-119

[13] Dynamic Changes in Dimensional Structures of Co-Complex Crystals [J].

Kondo, Atsushi ;

Nakagawa, Tomohiro ;

Kajiro, Hiroshi ;

Chinen, Ayako ;

Hattori, Yoshiyuki ;

Okino, Fujio ;

Ohba, Tomonori ;

Kaneko, Katsumi ;

Kanoh, Hirofumi .

INORGANIC CHEMISTRY, 2010, 49 (20) :9247-9252

[14] A POWDER TECHNIQUE FOR EVALUATION OF NONLINEAR OPTICAL MATERIALS [J].

KURTZ, SK ;

PERRY, TT .

IEEE JOURNAL OF QUANTUM ELECTRONICS, 1968, QE 4 (05) :333-+

[15] Synthesis of supramolecular metallo-amine-oxy acid systems via crystal disassembly/reassembly [J].

Latham, Kay ;

Mensforth, Emily J. ;

Rix, Colin J. ;

White, Jonathan M. .

CRYSTENGCOMM, 2009, 11 (07) :1343-1351

[16] Frameworks for extended solids: Geometrical design principles [J].

O'Keeffe, M ;

Eddaoudi, M ;

Li, HL ;

Reineke, T ;

Yaghi, OM .

JOURNAL OF SOLID STATE CHEMISTRY, 2000, 152 (01) :3-20

[17] Amine-templated open-framework zinc arsenates of varying dimensionalities: Synthesis, structure, polymorphism, and transformation reactions [J].

Rao, V. Koteswara ;

Chakrabarti, Sandip ;

Natarajan, Srinivasan .

INORGANIC CHEMISTRY, 2007, 46 (25) :10781-10790

[18] In situ recrystallisation of a coordination polymer with hemilabile linkers [J].

Richards, Philip I. ;

Bickley, Jamie F. ;

Boomishankar, Ramamoorthy ;

Steiner, Alexander .

CHEMICAL COMMUNICATIONS, 2008, (14) :1656-1658

[19] Crystal-to-crystal transformation from tri- to mononuclear Cu(II) complex with a sugar-derived ligand via proton transfer reaction and rearrangement of hydrogen bonding networks [J].

Sah, AK ;

Tanase, T .

CHEMICAL COMMUNICATIONS, 2005, (48) :5980-5981

[20] SHELXT - Integrated space-group and crystal-structure determination [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2015, 71 :3-8

← 1 2 3 →