Temperature-Dependent Crystal Self-Assembly, Disassembly, and Reassembly Among Three Cadmium(II) Carboxylate-Phosphinates

被引：40

作者：

Dong, Li-Jie ^{[1
]}

Zhao, Cui-Cui ^{[1
]}

Xu, Xiang ^{[2
]}

Du, Zi-Yi ^{[1
,2
]}

Xie, Yong-Rong ^{[1
]}

Zhang, Jian ^{[2
]}

机构：

[1] Gannan Normal Univ, Coll Chem & Chem Engn, Ganzhou 341000, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2012年 / 12卷 / 04期

关键词：

COORDINATION POLYMERS; STRUCTURAL TRANSFORMATIONS; NETWORKS; COMPLEX; LIGAND; STATE;

D O I：

10.1021/cg300029d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A metastable three-dimensional cadmium(II) coordination polymer with (2-carboxyethyl)(phenyl)phosphinate (12) and 4,4'-bipyridine (bipy) as ligands, namely, [Cd(L)(bipy)(H2O)(2)] (1), can be converted to two new two-dimensional/ three-dimensional varieties under hydrothermal treatments at different temperatures, that is, [Cd(L)(bipy)] (2) and [Cd(L)(bipy)(0.5)]center dot 0.5H(2)O (3). Their syntheses, crystal structures, structural transformations, and luminescent properties are presented. In addition, 1 shows a second harmonic generation response that is similar to 0.3 tames that of KDP (KH2PO4).

引用

页码：2052 / 2058

页数：7

共 25 条

[1] Reversible solid state structural transformation of a polyhapto lead(II) polymeric chain to a tetrahapto lead(II) two-dimensional network by thermal dehydration with no change in nanoplate morphology [J].

Akhbari, Kamran ;

Morsali, Ali .

CRYSTENGCOMM, 2011, 13 (06) :2047-2053

[2]

[Anonymous], 2008, APEX2 SADABS SAINT

[3] Structural transformations from a 1-D chain to two 3-D supramolecular isomers via crystal disassembly and reassembly [J].

Bai, Yue-Ling ;

Tao, Jun ;

Huang, Rong-Bin ;

Zheng, Lan-Sun .

CRYSTENGCOMM, 2008, 10 (05) :472-474

[4] A snapshot of a coordination polymer self- assembly process: the crystallization of a metastable 3D network followed by the spontaneous transformation in water to a 2D pseudopolymorphic phase [J].

Bataille, Thierry ;

Costantino, Ferdinando ;

Ienco, Andrea ;

Guerri, Annalisa ;

Marmottini, Fabio ;

Midollini, Stefano .

CHEMICAL COMMUNICATIONS, 2008, (47) :6381-6383

[5]

Birum G.H., 1978, U.S. Patent, Patent No. 4081463

[6] Structural interconversion between a chain polymer and a two-dimensional network accompanied by tunable magnetic properties [J].

Chen, Chao ;

Sun, Jian-Ke ;

Li, Wei ;

Chen, Chang-Neng ;

Zhang, Jie .

CHEMICAL COMMUNICATIONS, 2011, 47 (23) :6683-6685

[7] Destruction and reconstruction of the robust [Cu2(OOCR)4] unit during crystal structure transformations between two coordination polymers [J].

Du, Miao ;

Li, Cheng-Peng ;

Wu, Jing-Min ;

Guo, Jian-Hua ;

Wang, Gui-Chang .

CHEMICAL COMMUNICATIONS, 2011, 47 (28) :8088-8090

[8] Three novel zinc(II) sulfonate-phosphonates with tetranuclear or hexanuclear cluster units [J].

Du, Zi-Yi ;

Xu, Hai-Bing ;

Mao, Jiang-Gao .

INORGANIC CHEMISTRY, 2006, 45 (16) :6424-6430

[9] Two polymorphs of (2-carboxyethyl)(phenyl)phosphinic acid [J].

Hu, Qiao-Sheng ;

Zhang, Xiu-Zhi ;

Luo, Shu-Fen ;

Sun, Yu-Hui ;

Du, Zi-Yi .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2011, 67 :O195-O197

[10] Porous metal-organic frameworks as platforms for functional applications [J].

Jiang, Hai-Long ;

Xu, Qiang .

CHEMICAL COMMUNICATIONS, 2011, 47 (12) :3351-3370

← 1 2 3 →