Rhodium and Iridium Fluorido and Bifluorido Complexes Derived from Peroxido Precursors

被引：23
作者：
Baumgarth, Hanna [1 ]
Meier, Gregor [1 ]
Braun, Thomas [1 ]
Braun-Cula, Beatrice [1 ]
机构：
[1] Humboldt Univ, Dept Chem, Brook Taylor Str 2, D-12489 Berlin, Germany
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2016年 / 28期
关键词：
Rhodium; Iridium; Fluorine; Peroxido ligands; F BOND ACTIVATION; DONOR-ACCEPTOR PROPERTIES; C-F; REDUCTIVE ELIMINATION; DISTANCE DEPENDENCE; OXIDATIVE ADDITION; HYDRIDE BIFLUORIDE; XENON DIFLUORIDE; REACTIVITY; FLUORINATION;
D O I：
10.1002/ejic.201600682
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The rhodium and iridium fluorido bifluorido complexes trans-[Rh(4-C5F4N)(F)(FHF)(CNtBu)(PEt3)(2)] (1) and trans-[Ir(4-C5F4N)(F)(FHF)(CNtBu)(PiPr(3))(2)] (2) have been synthesized by protonation of the peroxido complexes trans-[M(4-C5F4N)(O-2)(CNtBu)(PR3)(2)] with an HF source (M = Rh, R = Et; M = Ir, R = iPr). Abstraction of the coordinated HF resulted in the formation of the difluorido compounds trans-[M(4-C5F4N)(F)(2)(CNtBu)(PR3)(2)] (4: M = Rh, R = Et; 5: M = Ir, R = iPr).
引用
收藏
页码：4565 / 4572
页数：8
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