Bell-Boudoir and Water Gas Shift Reactions under Conditions of the Fischer-Tropsch Synthesis

被引：4
|
作者：
Lapidus, A. L. [1 ]
Eliseev, O. L. [2 ]
Kryuchkov, M. V. [1 ]
机构：
[1] Gubkin Russian State Univ Oil & Gas, Moscow 117917, Russia
[2] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia
来源：
SOLID FUEL CHEMISTRY | 2011年 / 45卷 / 05期
关键词：
Cetane Number; Solid Fuel Chemistry; Cobalt Catalyst; Tropsch Synthesis; Diesel Fraction;
D O I：
10.3103/S0361521911050041
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Underground coal gasification gases contain CO and H-2; therefore, they can be used as raw materials in the Fischer-Tropsch synthesis of higher hydrocarbons. The profitability can be increased by decreasing the selectivity of this process for undesirable products. The water gas shift and Bell-Boudoir reactions are considered; CO2 is formed as a result of these reactions. Promoted and unpromoted cobalt catalysts on the basis of silica gel and aluminum oxide were tested. The processes occurring on these samples were evaluated quantitatively under the conditions that simulate the Fischer-Tropsch synthesis.
引用
收藏
页码：313 / 315
页数：3
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