Alkane activation at ambient temperatures: Unusual selectivities, C-C, C-H bond scission versus C-C bond coupling

被引：16

作者：

Trionfetti, Cristiano ^{[1
]}

Agiral, Anil ^{[2
]}

Gardeniers, Han J. G. E. ^{[2
]}

Lefferts, Leon ^{[1
]}

Seshan, Kulathuiyer ^{[1
]}

机构：

[1] Univ Twente, Dept Sci & Technol, NL-7500 AE Enschede, Netherlands

[2] MESA Inst Nanotechnol, NL-7500 AE Enschede, Netherlands

来源：

CHEMPHYSCHEM | 2008年 / 9卷 / 04期

关键词：

alkanes; C-H activation; microreactors; plasma chemistry; radical ions;

D O I：

10.1002/cphc.200700757

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

(Graph Presented) Activating bonds: A cold plasma generated by dielectric barrier discharge in a microreactor converts alkanes (C1-C 3) at atmospheric pressure (see figure). Large amounts of products with higher molecular weight than the starting hydrocarbons are observed showing that C-H activation at lower T favourably leads to C-C bond formation. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：533 / 537

页数：5

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