Aerobic oxidation of cyclohexanol to cyclohexanone in compressed CO2 and liquid solvents

被引：17

作者：

Chang, YH ^{[1
]}

Jiang, T ^{[1
]}

Han, BX ^{[1
]}

Gao, LA ^{[1
]}

Zhang, R ^{[1
]}

Liu, ZM ^{[1
]}

Wu, WZ ^{[1
]}

机构：

[1] Chinese Acad Sci, Ctr Mol Sci, Beijing 100080, Peoples R China

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2003年 / 42卷 / 25期

关键词：

D O I：

10.1021/ie030040m

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The aerobic oxidation of cyclohexanol to cyclohexanone was conducted in compressed CO2 With a copper-based catalyst, and the effect of phase behavior and a small amount of cosolvents (toluene or fluorobenzene) on the conversion and selectivity of the reaction in supercritical (SC) CO2 was studied. To explore the advantages of the reaction in compressed CO2, the reaction was also performed in liquid toluene and fluorobenzene and in the absence of solvent for comparison. The results indicated that the selectivity of the reaction in compressed CO2 with and without cosolvents was much higher than that in the liquid solvents or without solvent. The conversion of cyclohexanol was improved effectively by adding a small amount of the cosolvents and the selectivity for the desired product was still very high. It was advantageous to carry out the reaction in CO2.

引用

页码：6384 / 6388

页数：5

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