A facile synthesis of mesoporous Co3O4/CeO2 hybrid nanowire arrays for high performance supercapacitors

被引:114
作者
Cui, Jiewu [1 ,2 ]
Zhang, Xinyi [3 ]
Tong, Liang [2 ]
Luo, Jinbao [1 ]
Wang, Yan [1 ,2 ]
Zhang, Yong [1 ,2 ]
Xie, Kui [1 ,2 ]
Wu, Yucheng [1 ,2 ]
机构
[1] Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230009, Peoples R China
[2] Key Lab Adv Funct Mat & Devices Anhui Prov, Hefei 230009, Peoples R China
[3] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia
基金
中国国家自然科学基金;
关键词
NI FOAM; ELECTRODES; GROWTH; NANOSTRUCTURES; NANOTUBES; ULTRATHIN; DESIGN;
D O I
10.1039/c5ta00860c
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The development of porous yet densely packed nanomaterials with high ion-accessible surface area and long cycling life is critical to the realization of high-density electrochemical capacitive energy storage. In this paper, we report a facile hydrothermal method to fabricate Co3O4/CeO2 hybrid nanowire arrays (NWAs). Supercapacitors based on the as-prepared mesoporous Co3O4/CeO2 hybrid NWAs exhibit excellent pseudocapacitive performance with a capacitance of 4.98 F cm(-2) at 10 mA cm(-2) (1037.5 F g(-1) at 2.08 A g(-1)) and only a small capacitance loss of 5.6% after 5000 charge/discharge cycles. The remarkable pseudocapacitance and superior stability suggest that mesoporous Co3O4/CeO2 hybrid NWAs are promising candidates for supercapacitor applications.
引用
收藏
页码:10425 / 10431
页数:7
相关论文
共 42 条
[1]   A facile method to improve the high rate capability of Co3O4 nanowire array electrodes [J].
Cheng, Hua ;
Lu, Zhou Guang ;
Deng, Jian Qiu ;
Chung, C. Y. ;
Zhang, Kaili ;
Li, Yang Yang .
NANO RESEARCH, 2010, 3 (12) :895-901
[2]   3D Graphene-Cobalt Oxide Electrode for High-Performance Supercapacitor and Enzymeless Glucose Detection [J].
Dong, Xiao-Chen ;
Xu, Hang ;
Wang, Xue-Wan ;
Huang, Yin-Xi ;
Chan-Park, Mary B. ;
Zhang, Hua ;
Wang, Lian-Hui ;
Huang, Wei ;
Chen, Peng .
ACS NANO, 2012, 6 (04) :3206-3213
[3]   Hybrid structure of cobalt monoxide nanowire @ nickel hydroxidenitrate nanoflake aligned on nickel foam for high-rate supercapacitor [J].
Guan, Cao ;
Liu, Jinping ;
Cheng, Chuanwei ;
Li, Hongxing ;
Li, Xianglin ;
Zhou, Weiwei ;
Zhang, Hua ;
Fan, Hong Jin .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (11) :4496-4499
[4]   Hierarchical Co3O4@PPy@MnO2 core-shell-shell nanowire arrays for enhanced electrochemical energy storage [J].
Han, Lijuan ;
Tang, Pengyi ;
Zhang, Li .
NANO ENERGY, 2014, 7 :42-51
[5]   Design and tailoring of the nanotubular arrayed architecture of hydrous RuO2 for next generation supercapacitors [J].
Hu, Chi-Chang ;
Chang, Kuo-Hsin ;
Lin, Ming-Champ ;
Wu, Yung-Tai .
NANO LETTERS, 2006, 6 (12) :2690-2695
[6]   Hierarchical porous NiCo2O4 nanowires for high-rate supercapacitors [J].
Jiang, Hao ;
Ma, Jan ;
Li, Chunzhong .
CHEMICAL COMMUNICATIONS, 2012, 48 (37) :4465-4467
[7]   Incorporation of MnO2-Coated Carbon Nanotubes between Graphene Sheets as Supercapacitor Electrode [J].
Lei, Zhibin ;
Shi, Fuhua ;
Lu, Li .
ACS APPLIED MATERIALS & INTERFACES, 2012, 4 (02) :1058-1064
[8]   Co3O4 Nanowire@MnO2 Ultrathin Nanosheet Core/Shell Arrays: A New Class of High-Performance Pseudocapacitive Materials [J].
Liu, Jinping ;
Jiang, Jian ;
Cheng, Chuanwei ;
Li, Hongxing ;
Zhang, Jixuan ;
Gong, Hao ;
Fan, Hong Jin .
ADVANCED MATERIALS, 2011, 23 (18) :2076-+
[9]   Ultrathin and Lightweight 3D Free-Standing Ni@NiO Nanowire Membrane Electrode for a Supercapacitor with Excellent Capacitance Retention at High Rates [J].
Liu, Nishuang ;
Li, Jian ;
Ma, Wenzhen ;
Liu, Weijie ;
Shi, Yuling ;
Tao, Jiayou ;
Zhang, Xianghui ;
Su, Jun ;
Li, Luying ;
Gao, Yihua .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (16) :13627-13634
[10]   Extraordinarily high pseudocapacitance of metal organic framework derived nanostructured cerium oxide [J].
Maiti, Sandipan ;
Pramanik, Atin ;
Mahanty, Sourindra .
CHEMICAL COMMUNICATIONS, 2014, 50 (79) :11717-11720